Ruthenium(II) Polyimine Complexes with a Long-Lived 3IL Excited State or a 3MLCT/3IL Equilibrium: Efficient Triplet Sensitizers for Low-Power Upconversion

被引：210

作者：

Ji, Shaomin ^{[1
]}

Wu, Wanhua ^{[1
]}

Wu, Wenting ^{[1
]}

Guo, Huimin ^{[1
]}

Zhao, Jianzhang ^{[1
]}

机构：

[1] Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 07期

关键词：

photochemistry; pyrene; ruthenium; triplet excited states; upconversion; PHOTOPHYSICAL BEHAVIOR; VISIBLE-LIGHT; CHROMOPHORE; GENERATION; MLCT;

D O I：

10.1002/anie.201006192

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Up, up, and away! The long-lived 3IL excited states of Ru II polyimine complexes were found to be more efficient in sensitizing upconversion based on triplet-triplet annihilation (TTA) and energy transfer (TTET) than the shorter-lived 3MLCT excited states (see picture). Upconversion occurs with an anti-Stokes shift of up to 0.77a eV. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1626 / 1629

页数：4

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