Solid state metathesis reaction for metal borides, silicides, pnictides and chalcogenides: Ionic or elemental pathways

被引：264

作者：

Parkin, IP

机构：

[1] Department of Chemistry, University College London, Christopher Ingold Laboratory, London WC1H 0AJ

来源：

CHEMICAL SOCIETY REVIEWS | 1996年 / 25卷 / 03期

关键词：

D O I：

10.1039/cs9962500199

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solid rate metathesis reactions offer a rapid, low external energy route to a range of inorganic ceramic materials including nitrides, oxides, pnictides, chalcogenides, silicides and borides. The reactions can be filament or bulk thermally initiated and often proceed with a thermal flash or propagation wave. The reactions can follow either an ionic metathetical or a reductive recombination pathway.

引用

页码：199 / +