学术探索
学术期刊
新闻热点
数据分析
智能评审

Solid state metathesis reaction for metal borides, silicides, pnictides and chalcogenides: Ionic or elemental pathways

被引：264
作者：
Parkin, IP
机构：
[1] Department of Chemistry, University College London, Christopher Ingold Laboratory, London WC1H 0AJ
来源：
CHEMICAL SOCIETY REVIEWS | 1996年 / 25卷 / 03期
关键词：
D O I：
10.1039/cs9962500199
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Solid rate metathesis reactions offer a rapid, low external energy route to a range of inorganic ceramic materials including nitrides, oxides, pnictides, chalcogenides, silicides and borides. The reactions can be filament or bulk thermally initiated and often proceed with a thermal flash or propagation wave. The reactions can follow either an ionic metathetical or a reductive recombination pathway.
引用
收藏
页码：199 / +
相关论文
共 44 条
  • [11] Synthesis of metal silicide powders by thermolysis of metal chlorides with magnesium silicide
    Fitzmaurice, JC
    Hector, AL
    Parkin, IP
    Rowley, AT
    [J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1995, 101 (1-4): : 47 - 55
  • [12] METATHESIS ROUTES TO LANTHANIDE PNICTIDES
    FITZMAURICE, JC
    PARKIN, IP
    ROWLEY, AT
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 1994, 4 (02) : 285 - 289
  • [13] LOW-TEMPERATURE ROUTES TO EARLY TRANSITION-METAL NITRIDES
    FITZMAURICE, JC
    HECTOR, AL
    PARKIN, IP
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (16): : 2435 - 2438
  • [14] FITZMAURICE JC, 1994, MAIN GROUP MET CHEM, V17, P7
  • [15] FITZMAURICE JC, 1994, MAIN GROUP MET CHEM, V17, P537
  • [16] RAPID SOLID-STATE SYNTHESIS OF REFRACTORY NITRIDES
    GILLAN, EG
    KANER, RB
    [J]. INORGANIC CHEMISTRY, 1994, 33 (25) : 5693 - 5700
  • [17] LOW-TEMPERATURE SOLID-STATE ROUTES TO TRANSITION-METAL OXIDES VIA METATHESIS REACTIONS INVOLVING LITHIUM-OXIDE
    HECTOR, A
    PARKIN, IP
    [J]. POLYHEDRON, 1993, 12 (15) : 1855 - 1862
  • [18] SELF-PROPAGATING ROUTES TO TRANSITION-METAL PHOSPHIDES
    HECTOR, AL
    PARKIN, IP
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 1994, 4 (02) : 279 - 283
  • [19] TRANSITION-METAL PNICTIDE SYNTHESIS - SELF-PROPAGATING REACTIONS INVOLVING SODIUM ARSENIDE, ANTIMONIDE AND BISMUTHIDE
    HECTOR, AL
    PARKIN, IP
    [J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1994, 49 (04): : 477 - 482
  • [20] SODIUM-AZIDE AS A REAGENT FOR SOLID-STATE METATHESIS PREPARATIONS OF REFRACTORY-METAL NITRIDES
    HECTOR, AL
    PARKIN, IP
    [J]. POLYHEDRON, 1995, 14 (07) : 913 - 917
12345