Geometrical preferences of complexes of terpyridine N-oxide ligands:: synthesis and crystal structures of nickel(II) with terpyridine 1,1',1"-trioxide, terpyridine 1,1"-dioxide and terpyridine 1-oxide

被引：10

作者：

Amoroso, AJ

Burrows, MW

Dickinson, AA

Jones, C

Willock, DJ

Wong, WT

机构：

[1] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales

[2] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 03期

关键词：

coordination chemistry; density functional calculations; isomerism; molecular modelling; stereochemistry;

D O I：

10.1039/b008993l

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[NiL2][ClO4](2) complexes (L = terpyridine 1,1',1 " -trioxide, terpyridine 1,1 " -dioxide and terpyridine 1-oxide) have been prepared and crystallographically characterised; data shows a predictable variation in ligand conformation, such as facial or meridonal binding, which is in agreement with DFT calculations.

引用

页码：225 / 227

页数：3

共 18 条

[11] 2,2'-BIPYRIDINE 1,1'-DIOXIDE AND 2,2',2''-TERPYRIDINE 1,1',1''-TRIOXIDE COMPLEXES OF MANGANESE(II), MANGANESE(III), AND MANGANESE(IV) [J].