Star-burst prisms with cyclotriveratrylene-type ligands:: A [Pd6L8]12+ stella octangular structure

被引：111

作者：

Ronson, Tanya K. ^{[1
]}

Fisher, Julie ^{[1
]}

Harding, Lindsay P. ^{[2
]}

Hardie, Michaele J. ^{[1
]}

机构：

[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

[2] Univ Huddersfield, Dept Chem & Biol Sci, Huddersfield HD1 3DH, W Yorkshire, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 47期

基金：

英国工程与自然科学研究理事会;

关键词：

coordination modes; metallo-supramolecular cage; self-assembly; structure elucidation; supramolecular chemistry;

D O I：

10.1002/anie.200703903

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Star treatment: Host molecule tris(isonicotinoyl)cyclotriguaiacylene self-assembles with Pd(NO3)2 to form a [Pd 6L8]12+ metallo-supramolecular cage of over 3 nm in diameter that resembles a stella octangular structure (see picture). ESMS and DOSY NMR studies show the assembly also exists in solution with a hydrodynamic radius of approximately 19 Å. (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9086 / 9088

页数：3

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