Star-burst prisms with cyclotriveratrylene-type ligands:: A [Pd6L8]12+ stella octangular structure

被引：111

作者：

Ronson, Tanya K. ^{[1
]}

Fisher, Julie ^{[1
]}

Harding, Lindsay P. ^{[2
]}

Hardie, Michaele J. ^{[1
]}

机构：

[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

[2] Univ Huddersfield, Dept Chem & Biol Sci, Huddersfield HD1 3DH, W Yorkshire, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 47期

基金：

英国工程与自然科学研究理事会;

关键词：

coordination modes; metallo-supramolecular cage; self-assembly; structure elucidation; supramolecular chemistry;

D O I：

10.1002/anie.200703903

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Star treatment: Host molecule tris(isonicotinoyl)cyclotriguaiacylene self-assembles with Pd(NO3)2 to form a [Pd 6L8]12+ metallo-supramolecular cage of over 3 nm in diameter that resembles a stella octangular structure (see picture). ESMS and DOSY NMR studies show the assembly also exists in solution with a hydrodynamic radius of approximately 19 Å. (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9086 / 9088

页数：3

共 51 条

[21] Interwoven 2-D coordination network prepared from the molecular host tris(isonicotinoyl)cyclotriguaiacylene and silver(I) cobalt(III) bis(dicarbollide) [J].

Hardie, MJ ;

Sumby, CJ .

INORGANIC CHEMISTRY, 2004, 43 (22) :6872-6874

[22]

Hardie MJ, 2000, ANGEW CHEM INT EDIT, V39, P3835, DOI 10.1002/1521-3773(20001103)39:21<3835::AID-ANIE3835>3.0.CO

[23]

2-Q

[24]

Hardie MJ, 2000, CHEM-EUR J, V6, P3293, DOI 10.1002/1521-3765(20000901)6:17<3293::AID-CHEM3293>3.3.CO

[25]

2-W

[26]

HARDIE MJ, 2000, ANGEW CHEM, V112, P3993

[27]

Hiraoka S., 2006, ANGEW CHEM, V118, P6638

[28] Isostructural coordination capsules for a series of 10 different d5-d10 transition-metal ions [J].

Hiraoka, Shuichi ;

Harano, Koji ;

Shiro, Motoo ;

Ozawa, Yoshiki ;

Yasuda, Nobuhiro ;

Toriumi, Koshiro ;

Shionoya, Mitsuhiko .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (39) :6488-6491

[29] Saccharide-coated M12L24 molecular spheres that form aggregates by multi-interaction with proteins [J].

Kamiya, Nozomi ;

Tominaga, Masahide ;

Sato, Sota ;

Fujita, Makoto .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (13) :3816-+

[30] Complete selection of a self-assembling homo- or hetero-cavitand cage via metal coordination based on ligand tuning [J].

Kobayashi, K ;

Yamada, Y ;

Yamanaka, M ;

Sei, Y ;

Yamaguchi, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (43) :13896-13897

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