Star-burst prisms with cyclotriveratrylene-type ligands:: A [Pd6L8]12+ stella octangular structure

被引：111

作者：

Ronson, Tanya K. ^{[1
]}

Fisher, Julie ^{[1
]}

Harding, Lindsay P. ^{[2
]}

Hardie, Michaele J. ^{[1
]}

机构：

[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

[2] Univ Huddersfield, Dept Chem & Biol Sci, Huddersfield HD1 3DH, W Yorkshire, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 47期

基金：

英国工程与自然科学研究理事会;

关键词：

coordination modes; metallo-supramolecular cage; self-assembly; structure elucidation; supramolecular chemistry;

D O I：

10.1002/anie.200703903

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Star treatment: Host molecule tris(isonicotinoyl)cyclotriguaiacylene self-assembles with Pd(NO3)2 to form a [Pd 6L8]12+ metallo-supramolecular cage of over 3 nm in diameter that resembles a stella octangular structure (see picture). ESMS and DOSY NMR studies show the assembly also exists in solution with a hydrodynamic radius of approximately 19 Å. (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9086 / 9088

页数：3

共 51 条

[11] Self-assembly of a novel pentanuclear centred-tetrahedral silver species [J].

Constable, EC ;

Housecroft, CE ;

Neuburger, M ;

Reymann, S ;

Schaffner, S .

CHEMICAL COMMUNICATIONS, 2004, (09) :1056-1057

[12] Resorcinarenes are hexameric capsules in solution [J].

Evan-Salem, Tamar ;

Baruch, Inbal ;

Avram, Liat ;

Cohen, Yoram ;

Palmer, Liam C. ;

Rebek, Julius, Jr. .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2006, 103 (33) :12296-12300

[13]

Fox O. D., 2000, ANGEW CHEM, V112, P139

[14] Cadmium- and zinc-directed assembly of nano-sized, resorcarene-based host architectures which strongly bind C60 [J].

Fox, OD ;

Drew, MGB ;

Wilkinson, EJS ;

Beer, PD .

CHEMICAL COMMUNICATIONS, 2000, (05) :391-392

[15]

Fox OD, 2000, ANGEW CHEM INT EDIT, V39, P136

[16] Molecular paneling via coordination [J].

Fujita, M ;

Umemoto, K ;

Yoshizawa, M ;

Fujita, N ;

Kusukawa, T ;

Biradha, K .

CHEMICAL COMMUNICATIONS, 2001, (06) :509-518

[17] Chiral trialkanolamine-based hemicryptophanes: Synthesis and oxovanadium complex [J].

Gautier, A ;

Mulatier, JC ;

Crassous, J ;

Dutasta, JP .

ORGANIC LETTERS, 2005, 7 (07) :1207-1210

[18] Self-assembly of molecular nanoball: Design, synthesis, and characterization [J].

Ghosh, Sushobhan ;

Mukherjee, Partha Sarathi .

JOURNAL OF ORGANIC CHEMISTRY, 2006, 71 (22) :8412-8416

[19] A new self-assembling capsule via metal coordination [J].

Haino, T ;

Kobayashi, M ;

Chikaraishi, M ;

Fukazawa, Y .

CHEMICAL COMMUNICATIONS, 2005, (18) :2321-2323

[20] Network structures of cyclotriveratrylene and its derivatives [J].

Hardie, MJ ;

Ahmad, R ;

Sumby, CJ .

NEW JOURNAL OF CHEMISTRY, 2005, 29 (10) :1231-1240

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