Chemistry of a geminal frustrated Lewis pair featuring electron withdrawing C6F5 substituents at both phosphorus and boron

被引：105

作者：

Stute, Annika ^{[1
]}

Kehr, Gerald ^{[1
]}

Froehlichz, Roland ^{[1
]}

Erker, Gerhard ^{[1
]}

机构：

[1] Univ Munster, Inst Organ Chem, Corrensstr 40, D-48149 Munster, Germany

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 14期

关键词：

BIS(PENTAFLUOROPHENYL)BORANE; DIHYDROGEN;

D O I：

10.1039/c1cc10241a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydroboration of the electron poor phosphine (1-propenyl)P(C6F5)(2) with Piers' borane [HB(C6F5)(2)] gave the geminal frustrated Lewis pair (C6F5)(2)P-CH(Et)-B(C6F5)(2). It undergoes 1,2-addition reactions to an alkene and an alkyne and to the C=N bond of an isocyanate. With mesityl azide it undergoes a 1,3-addition reaction.

引用

页码：4288 / 4290

页数：3

共 32 条

[1] REACTION OF 1,2-BORYLPHOSPHINOETHENE WITH PHENYL ISOCYANATE AND THE STRUCTURE OF THE REACTION-PRODUCTS [J].

ARBUZOV, BA ;

NIKONOV, GN ;

BALUEVA, AS ;

KAMALOV, RM ;

PUDOVIK, MA ;

SHAGIDULLIN, RR ;

PLYAMOVATYI, AK ;

KHADIULLIN, RS .

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1991, 40 (10) :2099-2102

[2] Structure and Dynamic Features of an Intramolecular Frustrated Lewis Pair [J].

Axenov, Kirill V. ;

Moemming, Cornelia M. ;

Kehr, Gerald ;

Froehlich, Roland ;

Erker, Gerhard .

CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (47) :14069-14073

[3] Photoisomerizable heterodienes derived from a phosphine borane [J].

Bebbington, Magnus W. P. ;

Bontemps, Sebastien ;

Bouhadir, Ghenwa ;

Bourissou, Didier .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (18) :3333-3336

[4]

Becer C.R., 2009, Angew. Chem, V121, P4998

[5] Studies in stereochemistry I Steric strains as a factor in the relative stability of some coordination compounds of boron [J].

Brown, HC ;

Schlesinger, HI ;

Cardon, SZ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1942, 64 :325-329

[6] Coordination chemistry of organic azides and amination reactions catalyzed by transition metal complexes [J].

Cenini, Sergio ;

Gallo, Emma ;

Caselli, Alessandro ;

Ragaini, Fabio ;

Fantauzzi, Simone ;

Piangiolino, Cristiana .

COORDINATION CHEMISTRY REVIEWS, 2006, 250 (11-12) :1234-1253

[7] AROMATIC FLUORODERIVATIVES .95. THE INVESTIGATION OF THE BEHAVIOR OF THE POLYFLUOROAROMATIC COMPOUNDS CONTAINING GROUP VA ELEMENTS IN ACID-MEDIA [J].

FURIN, GG ;

KRUPODER, SA ;

REZVUKHIN, AI ;

KILINA, TM ;

YAKOBSON, GG .

JOURNAL OF FLUORINE CHEMISTRY, 1983, 22 (04) :345-375

[8] A novel addition mechanism for the reaction of "Frustrated Lewis Pairs" with olefins [J].

Guo, Yong ;

Li, Shuhua .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (16) :2501-2505

[9]

HORN HG, 1976, CHEM ZTG, V100, P197

[10] Borylated Methylenephosphonium Salts: Precursors of Elusive Boryl(phosphino)carbenes [J].

Lavigne, Florie ;

Maerten, Eddy ;

Alcaraz, Gilles ;

Saffon-Merceron, Nathalie ;

Acosta-Silva, Carles ;

Branchadell, Vicenc ;

Baceiredo, Antoine .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (26) :8864-+

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