Ruthenium-catalyzed aerobic oxidative coupling of alkynes with 2-aryl-substituted pyrroles

被引：171

作者：

Ackermann, Lutz ^{[1
]}

Wang, Lianhui ^{[1
]}

Lygin, Alexander V. ^{[1
]}

机构：

[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany

来源：

CHEMICAL SCIENCE | 2012年 / 3卷 / 01期

关键词：

C BOND FORMATION; INDOLE SYNTHESES; DIRECT ARYLATION; H ACTIVATION; FUNCTIONALIZATION; ALKALOIDS; CLEAVAGE; LAMELLARINS; ALKENE; AIR;

D O I：

10.1039/c1sc00619c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ruthenium-catalyzed aerobic oxidative annulations of alkynes were accomplished with co-catalytic amounts of Cu(OAc)(2)center dot H2O under ambient air. The C-H/N-H bond functionalization occurred with unparalleled selectivities and ample scope to deliver structural analogs of bioactive marine alkaloids.

引用

页码：177 / 180

页数：4

共 55 条

[51] Ru-catalyzed oxidative coupling of arenes with olefins using O2
Weissman, H
Song, XP
Milstein, D
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (02) : 337 - 338
[52] Transition Metal Catalyzed Alkene and Alkyne Hydroacylation
Willis, Michael C.
[J]. CHEMICAL REVIEWS, 2010, 110 (02) : 725 - 748
[53] Palladium catalyzed synthesis of highly substituted naphthalenes via direct ring construction from amides with alkynes
Wu, Junliang
Cui, Xiuling
Mi, Xia
Li, Ying
Wu, Yangjie
[J]. CHEMICAL COMMUNICATIONS, 2010, 46 (36) : 6771 - 6773
[54] Catalytic Dehydrogenative Cross-Coupling: Forming Carbon-Carbon Bonds by Oxidizing Two Carbon-Hydrogen Bonds
Yeung, Charles S.
Dong, Vy M.
[J]. CHEMICAL REVIEWS, 2011, 111 (03) : 1215 - 1292
[55] Cross-Dehydrogenative Coupling Reactions of sp3-Hybridized C-H Bonds
Yoo, Woo-Jin
Li, Chao-Jun
[J]. C-H ACTIVATION, 2010, 292 : 281 - 302

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