Oxidative free radical reactions between 2-benzyl-1,4-naphthoquinones and β-dicarbonyl compounds

被引：29

作者：

Tsai, AI ^{[1
]}

Wu, YL ^{[1
]}

Chuang, CP ^{[1
]}

机构：

[1] Natl Cheng Kung Univ, Dept Chem, Tainan 70101, Taiwan

来源：

TETRAHEDRON | 2001年 / 57卷 / 37期

关键词：

manganese(III) acetate; cerium(IV) ammonium nitrate; oxidative; free radical; 2-benzyl-1,4-naphthoquinone;

D O I：

10.1016/S0040-4020(01)00754-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxidative free radical reactions between 2-benzyl-1,4-naphthoquinones and beta -dicarbonyl compounds are described. Electrophilic carbon-centered radicals produced by the manganese(EEL) acetate or cerium(IV) ammonium nitrate oxidation of beta -dicarbonyl compounds undergo efficient addition to a C-C double bond of quinone ring. This free radical reaction provides a novel method for the synthesis of naphthacene-5,12-diones. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：7829 / 7837

页数：9

共 34 条

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