Bis(enediyne) macrocycles: Synthesis, reactivity, and structural analysis

被引：23

作者：

Blanchette, HS ^{[1
]}

Brand, SC ^{[1
]}

Naruse, H ^{[1
]}

Weakley, TJR ^{[1
]}

Haley, MM ^{[1
]}

机构：

[1] Univ Oregon, Dept Chem, Eugene, OR 97403 USA

来源：

TETRAHEDRON | 2000年 / 56卷 / 49期

关键词：

diynes; macrocycles; polyynes; annulenes;

D O I：

10.1016/S0040-4020(00)00932-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We describe below the syntheses of five macrocycles possessing two enediyne warheads, along with the structural and thermal analyses of these bis(enediyne) compounds. The solid-stare packing of compound 6 suggests the possibility for the molecule to undergo a topochemical diacetylene polymerization. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：9581 / 9588

页数：8

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