Bis(enediyne) macrocycles: Synthesis, reactivity, and structural analysis

被引:23
作者
Blanchette, HS [1 ]
Brand, SC [1 ]
Naruse, H [1 ]
Weakley, TJR [1 ]
Haley, MM [1 ]
机构
[1] Univ Oregon, Dept Chem, Eugene, OR 97403 USA
关键词
diynes; macrocycles; polyynes; annulenes;
D O I
10.1016/S0040-4020(00)00932-7
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
We describe below the syntheses of five macrocycles possessing two enediyne warheads, along with the structural and thermal analyses of these bis(enediyne) compounds. The solid-stare packing of compound 6 suggests the possibility for the molecule to undergo a topochemical diacetylene polymerization. (C) 2000 Elsevier Science Ltd. All rights reserved.
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页码:9581 / 9588
页数:8
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