Olivine LiFePO4: development and future

被引:324
作者
Wang, Yonggang [1 ]
He, Ping [1 ]
Zhou, Haoshen [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Energy Technol Res Inst, Tsukuba, Ibaraki 3058568, Japan
关键词
LI-ION BATTERIES; RECHARGEABLE LITHIUM BATTERIES; POSITIVE-ELECTRODE MATERIALS; LIBOB EC/DEC ELECTROLYTES; ELECTROCHEMICAL PROPERTIES; CATHODE MATERIALS; ROOM-TEMPERATURE; NANOSTRUCTURED MATERIALS; THERMAL-STABILITY; UNSUPPORTED CLAIMS;
D O I
10.1039/c0ee00176g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In view of the limited oil storage and the global warming threats, it has been a worldwide topic to build a low carbon society supported by sustainable energy. As an effective energy storage device for the sustainable energy, the lithium-ion battery has been attracting wide attention. Olivine LiFePO4 has been considered as the most promising cathode candidate for the next-generation large-scale lithium-ion battery used for hybrid electric vehicles (HEVs) or electric vehicles (EVs), because of its inherent merits including low toxicity, potential for low cost, long cycle ability and high safety. From 1997 to present, continuous efforts have been made to understand and improve the performance of LiFePO4. Now, it seems that olivine LiFePO4 is ready for its big time. In the present paper, we review the development of LiFePO4 in the past years, and discuss some remaining problems for LiFePO4 in the future based on our current study.
引用
收藏
页码:805 / 817
页数:13
相关论文
共 69 条
[1]   Ionic and electronic transport in single crystalline LiFePO4 grown by optical floating zone technique [J].
Amin, R. ;
Maier, J. ;
Balaya, P. ;
Chen, D. P. ;
Lin, C. T. .
SOLID STATE IONICS, 2008, 179 (27-32) :1683-1687
[2]   High-temperature storage and cycling of C-LiFePO4/graphite Li-ion cells [J].
Amine, K ;
Liu, J ;
Belharouak, I .
ELECTROCHEMISTRY COMMUNICATIONS, 2005, 7 (07) :669-673
[3]   Thermal stability of LiFePO4-based cathodes [J].
Andersson, AS ;
Thomas, JO ;
Kalska, B ;
Häggström, L .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2000, 3 (02) :66-68
[4]   Nanostructured materials for advanced energy conversion and storage devices [J].
Aricò, AS ;
Bruce, P ;
Scrosati, B ;
Tarascon, JM ;
Van Schalkwijk, W .
NATURE MATERIALS, 2005, 4 (05) :366-377
[5]   Building better batteries [J].
Armand, M. ;
Tarascon, J. -M. .
NATURE, 2008, 451 (7179) :652-657
[6]   Nanomaterials for rechargeable lithium batteries [J].
Bruce, Peter G. ;
Scrosati, Bruno ;
Tarascon, Jean-Marie .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (16) :2930-2946
[7]   Response to "unsupported claims of ultrafast charging of Li-ion batteries" [J].
Ceder, G. ;
Kang, B. .
JOURNAL OF POWER SOURCES, 2009, 194 (02) :1024-1028
[8]   Hydrothermal synthesis of lithium iron phosphate [J].
Chen, Jiajun ;
Whittingham, M. Stanley .
ELECTROCHEMISTRY COMMUNICATIONS, 2006, 8 (05) :855-858
[9]   Combination of Lightweight Elements and Nanostructured Materials for Batteries [J].
Chen, Jun ;
Cheng, Fangyi .
ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (06) :713-723
[10]   Reducing carbon in LiFePO4/C composite electrodes to maximize specific energy, volumetric energy, and tap density [J].
Chen, ZH ;
Dahn, JR .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (09) :A1184-A1189