Palladium-tetraphosphine catalysed cross coupling of aryl bromides with arylboronic acids: remarkable influence of the nature of the ligand

被引：119

作者：

Feuerstein, M ^{[1
]}

Laurenti, D ^{[1
]}

Bougeant, C ^{[1
]}

Doucet, H ^{[1
]}

Santelli, M ^{[1
]}

机构：

[1] Fac Sci St Jerome, CNRS, Organ Synth Lab, F-13397 Marseille 20, France

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 04期

关键词：

D O I：

10.1039/b009520f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The cis,cis,cis-1,2,3,4-Tetrakis(diphenylphosphinomethyl)cyclopentane-[PdCl(C3H5)](2) system catalyses the cross coupling of aryl bromides with arylboronic acids with very high substrate-catalyst ratios in good yields; a turnover number of 28 000 000 can be obtained for the addition of 4-bromobenzophenone to benzeneboronic acid in the presence of this catalyst.

引用

页码：325 / 326

页数：2

共 16 条

[1] Orthopalladated triaryl phosphite complexes as highly active catalysts in biaryl coupling reactions
Albisson, DA
Bedford, RB
Lawrence, SE
Scully, PN
[J]. CHEMICAL COMMUNICATIONS, 1998, (19) : 2095 - 2096
[2] PALLADACYCLES AS EFFICIENT CATALYSTS FOR ARYL COUPLING REACTIONS
BELLER, M
FISCHER, H
HERRMANN, WA
OFELE, K
BROSSMER, C
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (17): : 1848 - 1849
[3] New structurally rigid palladium catalysts for the alternating copolymerization of carbon monoxide and ethene
Bianchini, C
Lee, HM
Meli, A
Oberhauser, W
Vizza, F
Brüggeller, P
Rainer, HB
Langes, C
[J]. CHEMICAL COMMUNICATIONS, 2000, (09) : 777 - 778
[4] Dramatic acceleration of the catalytic process of the amination of allyl acetates in the presence of a tetraphosphine/palladium system
Feuerstein, M
Laurenti, D
Doucet, H
Santelli, M
[J]. CHEMICAL COMMUNICATIONS, 2001, (01) : 43 - 44
[5] LAURENTI D, IN PRESS J ORG CHEM
[6] Malleron J.-L., 1997, HDB PALLADIUM CATALY, DOI DOI 10.1002/anie.201700889
[7] Donor-functionalized heterocyclic carbene complexes of palladium(II): Efficient catalysts for C-C coupling reactions
McGuinness, DS
Cavell, KJ
[J]. ORGANOMETALLICS, 2000, 19 (05) : 741 - 748
[8] PALLADIUM-CATALYZED CROSS-COUPLING REACTIONS OF ORGANOBORON COMPOUNDS
MIYAURA, N
SUZUKI, A
[J]. CHEMICAL REVIEWS, 1995, 95 (07) : 2457 - 2483
[9] Palladium catalyzed coupling of aryl chlorides with arylboronic acids
Shen, W
[J]. TETRAHEDRON LETTERS, 1997, 38 (32) : 5575 - 5578
[10] Catalytic cross-coupling reactions in biaryl synthesis
Stanforth, SP
[J]. TETRAHEDRON, 1998, 54 (3-4) : 263 - 303

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