One-pot oxidation and Wittig olefination of alcohols using O-iodoxybenzoic acid and stable Wittig ylide

被引：38

作者：

Maiti, A ^{[1
]}

Yadav, JS ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Organ Div, Hyderabad 500007, Andhra Pradesh, India

来源：

SYNTHETIC COMMUNICATIONS | 2001年 / 31卷 / 10期

关键词：

D O I：

10.1081/SCC-100104061

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Benylic, allylic, and propargylic alcohols, as well as diols, can be oxidized with o-iodoxybenzoic acid (IBX) in the presence of stabilized Wittig ylide to generate alpha,beta -unsaturated ester in one pot. This is useful when the intermediate aldehydes are unstable and difficult to isolate.

引用

页码：1499 / 1506

页数：8

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