Rhodium-catalyzed asymmetric 1,4-addition and its related asymmetric reactions

被引：1345

作者：

Hayashi, T ^{[1
]}

Yamasaki, K ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan

来源：

CHEMICAL REVIEWS | 2003年 / 103卷 / 08期

关键词：

D O I：

10.1021/cr020022z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The rhodium-catalyzed asymmetric 1,4-addition of organoboron reagents is developing quickly. The reaction can be carried out in an aqueous solvent and the enantioselectivity is very high, in most cases over 90% ee, at a reaction temperature of around 100°C. Thus, this reaction provides the best method for enantioselective introduction of aryl and alkenyl groups to β position of these electron deficient olefins.

引用

页码：2829 / 2844

页数：16

共 81 条

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