π-π Interaction intercalation of layered carbon materials with metallocene

被引：42

作者：

Gao, Yongjun ^{[1
,2
]}

Hu, Gang ^{[3
]}

Zhang, Wei ^{[1
]}

Ma, Ding ^{[1
]}

Bao, Xinhe ^{[2
]}

机构：

[1] Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China

[2] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

[3] Exponent Inc, Hangzhou 310053, Zhejiang, Peoples R China

来源：

DALTON TRANSACTIONS | 2011年 / 40卷 / 17期

基金：

中国国家自然科学基金;

关键词：

GRAPHITE OXIDE; GRAPHENE; NANOPARTICLES; NANOSHEETS; COMPLEXES; CATALYSTS; FILMS;

D O I：

10.1039/c0dt01392g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new hybrid material consisting of ferrocene and layered carbon (LC: graphene oxide (GO) or reduced graphene oxide (RGO)) was prepared through a facile intercalation approach. The structure of ferrocene was well maintained while the strong p-p interaction between LC and ferrocene remarkably suppressed the sublimation of ferrocene and promoted ferrocene to decompose into iron nanoparticles in between layers of LC. The hybrid exhibited excellent electrochemical properties in electrocatalytic oxidation of ascorbic acid (AA).

引用

页码：4542 / 4547

页数：6

共 29 条

[21] X-ray absorption spectroscopy (XAS) study of dip deposited a-C:H(OH) thin films [J].

Ray, SC ;

Tsai, HM ;

Chiou, JW ;

Bose, B ;

Jan, JC ;

Kumar, K ;

Pong, WF ;

Dasgupta, D ;

Tsai, MH .

JOURNAL OF PHYSICS-CONDENSED MATTER, 2004, 16 (32) :5713-5719

[22] Palladium Nanoparticles on Graphite Oxide and Its Functionalized Graphene Derivatives as Highly Active Catalysts for the Suzuki-Miyaura Coupling Reaction [J].

Scheuermann, Gil M. ;

Rumi, Luigi ;

Steurer, Peter ;

Bannwarth, Willi ;

Muelhaupt, Rolf .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (23) :8262-8270

[23] Exfoliated Graphene Separated by Platinum Nanoparticles [J].

Si, Yongchao ;

Samulski, Edward T. .

CHEMISTRY OF MATERIALS, 2008, 20 (21) :6792-6797

[24] Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide [J].

Stankovich, Sasha ;

Dikin, Dmitriy A. ;

Piner, Richard D. ;

Kohlhaas, Kevin A. ;

Kleinhammes, Alfred ;

Jia, Yuanyuan ;

Wu, Yue ;

Nguyen, SonBinh T. ;

Ruoff, Rodney S. .

CARBON, 2007, 45 (07) :1558-1565

[25] Comparative study of different types of graphenes as electrocatalysts for ascorbic acid [J].

Stergiou, Dimitrios V. ;

Diamanti, Evmorfia K. ;

Gournis, Dimitrios ;

Prodromidis, Mamas I. .

ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (10) :1307-1309

[26] Catalytic dehydrogenation of cyclooctane with titanium, zirconium and hafnium metallocene complexes [J].

Taubmann, Sandra ;

Denner, Christine E. ;

Alt, Helmut G. .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (13) :2005-2019

[27] A Graphene Hybrid Material Covalently Functionalized with Porphyrin: Synthesis and Optical Limiting Property [J].

Xu, Yanfei ;

Liu, Zhibo ;

Zhang, Xiaoliang ;

Wang, Yan ;

Tian, Jianguo ;

Huang, Yi ;

Ma, Yanfeng ;

Zhang, Xiaoyan ;

Chen, Yongsheng .

ADVANCED MATERIALS, 2009, 21 (12) :1275-+

[28]

Zhang XY, 2009, CHINESE J INORG CHEM, V25, P1903

[29] Experimental observation of the quantum Hall effect and Berry's phase in graphene [J].

Zhang, YB ;

Tan, YW ;

Stormer, HL ;

Kim, P .

NATURE, 2005, 438 (7065) :201-204

← 1 2 3 →