Porous Organic Polymers Based on Propeller-Like Hexaphenylbenzene Building Units

被引：115

作者：

Chen, Qi ^{[1
]}

Luo, Min ^{[1
,2
]}

Wang, Tao ^{[1
,3
]}

Wang, Jin-Xiang ^{[1
,2
]}

Zhou, Ding ^{[1
]}

Han, Ying ^{[2
]}

Zhang, Chang-Shan ^{[3
]}

Yan, Chao-Guo ^{[2
]}

Han, Bao-Hang ^{[1
]}

机构：

[1] Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China

[2] Yangzhou Univ, Coll Chem & Chem Engn, Yangzhou 225002, Peoples R China

[3] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Peoples R China

来源：

MACROMOLECULES | 2011年 / 44卷 / 14期

基金：

美国国家科学基金会;

关键词：

SURFACE-AREA; INTRINSIC MICROPOROSITY; GAS SORPTION; NETWORKS; DELOCALIZATION; FRAMEWORKS;

D O I：

10.1021/ma200915f

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Hexaphenylbenzene-based porous organic polymers are prepared smoothly through palladium-catalyzed C C coupling polymerization. According to the obtained nitrogen physisorption isotherms, the Brunauer Emmett-Teller-specific surface area for these polymers varies between 742 and 1148 m(2) g(-1). Gravimetric hydrogen adsorption isotherms show that the adsorption capacity for hydrogen is up to 1.5 wt % at 1.13 bar and 77 K Thanks to the propeller-like structure, unique electronic feature, and efficient preparation, hexaphenylbenzene can be taken as a promising building block for designing porous polymers with special properties.

引用

页码：5573 / 5577

页数：5

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