Hexaphenylbenzene-based polymers of intrinsic microporosity

被引:71
作者
Short, Rhys [1 ]
Carta, Mariolino [1 ]
Bezzu, C. Grazia [1 ]
Fritsch, Detlev [2 ]
Kariuki, Benson M. [1 ]
McKeown, Neil B. [1 ]
机构
[1] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, S Glam, Wales
[2] Helmholtz Zentrum Geesthacht, Inst Mat Res, D-21502 Geesthacht, Germany
基金
英国工程与自然科学研究理事会;
关键词
CRYSTALS; DERIVATIVES; ADSORPTION; MOLECULES; NETWORKS; CATIONS;
D O I
10.1039/c1cc11717c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Microporous polymers derived from the 1,2- and 1,4-regioisomers of di(3',4'-dihydroxyphenyl)tetraphenylbenzene have very different properties with the former being composed predominantly of cyclic oligomers whereas the latter is of high molar mass suitable for the formation of robust solvent-cast films of high gas permeability.
引用
收藏
页码:6822 / 6824
页数:3
相关论文
共 31 条
  • [1] Highly permeable polymers for gas separation membranes
    Budd, Peter M.
    McKeown, Neil B.
    [J]. POLYMER CHEMISTRY, 2010, 1 (01) : 63 - 68
  • [2] Gas permeation parameters and other physicochemical properties of a polymer of intrinsic microporosity: Polybenzodioxane PIM-1
    Budd, Peter M.
    McKeown, Neil B.
    Ghanem, Bader S.
    Msayib, Kadhum J.
    Fritsch, Detlev
    Starannikova, Ludmila
    Belov, Nikolai
    Sanfirova, Olga
    Yampolskii, Yuri
    Shantarovich, Victor
    [J]. JOURNAL OF MEMBRANE SCIENCE, 2008, 325 (02) : 851 - 860
  • [3] Polymers of intrinsic microporosity (PIMs): robust, solution-processable, organic nanoporous materials
    Budd, PM
    Ghanem, BS
    Makhseed, S
    McKeown, NB
    Msayib, KJ
    Tattershall, CE
    [J]. CHEMICAL COMMUNICATIONS, 2004, (02) : 230 - 231
  • [4] Solution-processed, organophilic membrane derived from a polymer of intrinsic microporosity
    Budd, PM
    Elabas, ES
    Ghanem, BS
    Makhseed, S
    McKeown, NB
    Msayib, KJ
    Tattershall, CE
    Wang, D
    [J]. ADVANCED MATERIALS, 2004, 16 (05) : 456 - +
  • [5] A nanoporous network polymer derived from hexaazatrinaphthylene with potential as an adsorbent and catalyst support
    Budd, PM
    Ghanem, B
    Msayib, K
    McKeown, NB
    Tattershall, C
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (11) : 2721 - 2726
  • [6] Novel spirobisindanes for use as precursors to polymers of intrinsic microporosity
    Carta, Mariolino
    Msayib, Kadhurn J.
    Budd, Peter M.
    McKeown, Neil B.
    [J]. ORGANIC LETTERS, 2008, 10 (13) : 2641 - 2643
  • [7] DIBENZO PARA DIOXIN
    CORDES, AW
    FAIR, CK
    [J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1974, B 30 (JUN15): : 1621 - 1623
  • [8] Structural Features in Crystals of Derivatives of Benzene with Multiple Contiguous Phenyl Substituents
    Gagnon, Eric
    Maris, Thierry
    Arseneault, Pierre-Marc
    Maly, Kenneth E.
    Wuest, James D.
    [J]. CRYSTAL GROWTH & DESIGN, 2010, 10 (02) : 648 - 657
  • [9] Tampering with Molecular Cohesion in Crystals of Hexaphenylbenzenes
    Gagnon, Eric
    Halperin, Shira D.
    Metivaud, Valerie
    Maly, Kenneth E.
    Wuest, James D.
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2010, 75 (02) : 399 - 406
  • [10] Star-like substituted hexaarylbenzenes:: synthesis and mesomorphic properties
    Geng, YH
    Fechtenkötter, A
    Müllen, K
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (06) : 1634 - 1641