Dominant role of tunneling resistance in the electrical conductivity of carbon nanotube-based composites

被引:390
作者
Li, Chunyu [1 ]
Thostenson, Erik T.
Chou, Tsu-Wei
机构
[1] Univ Delaware, Dept Mech Engn, Newark, DE 19716 USA
[2] Univ Delaware, Ctr Composite Mat, Newark, DE 19716 USA
基金
美国国家科学基金会;
关键词
D O I
10.1063/1.2819690
中图分类号
O59 [应用物理学];
学科分类号
摘要
The effect of nanotube/nanotube contact resistance on the electrical conductivity of carbon nanotube-based nanocomposites is studied. The tunneling resistance due to an insulating film of matrix material between crossing nanotubes is calculated by assuming a rectangular potential barrier in the insulating film. Monte Carlo simulations indicate that the tunneling resistance plays a dominant role in the electrical conductivity of composites, and the maximum tunneling distance is found to be about 1.8 nm. Electrical conductivities of composites with inplane random distributions of carbon nanotubes follow the scaling law and the critical exponent depends on the level of contact resistance. (C) 2007 American Institute of Physics.
引用
收藏
页数:3
相关论文
共 26 条
[1]   Electrical conductivity and dielectric properties of multiwalled carbon nanotube and alumina composites [J].
Ahmad, Kaleem ;
Pan, Wei ;
Shi, Sui-Lin .
APPLIED PHYSICS LETTERS, 2006, 89 (13)
[2]   TUNNELING AND NONUNIVERSAL CONDUCTIVITY IN COMPOSITE-MATERIALS [J].
BALBERG, I .
PHYSICAL REVIEW LETTERS, 1987, 59 (12) :1305-1308
[3]   A comprehensive picture of the electrical phenomena in carbon black-polymer composites [J].
Balberg, I .
CARBON, 2002, 40 (02) :139-143
[4]   Electronic properties of single-walled carbon nanotube networks [J].
Bekyarova, E ;
Itkis, ME ;
Cabrera, N ;
Zhao, B ;
Yu, AP ;
Gao, JB ;
Haddon, RC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (16) :5990-5995
[5]   Very low conductivity threshold in bulk isotropic single-walled carbon nanotube-epoxy composites [J].
Bryning, MB ;
Islam, MF ;
Kikkawa, JM ;
Yodh, AG .
ADVANCED MATERIALS, 2005, 17 (09) :1186-+
[6]   Contact resistance between carbon nanotubes [J].
Buldum, A ;
Lu, JP .
PHYSICAL REVIEW B, 2001, 63 (16)
[7]   Percolation-dominated conductivity in a conjugated-polymer-carbon-nanotube composite [J].
Coleman, JN ;
Curran, S ;
Dalton, AB ;
Davey, AP ;
McCarthy, B ;
Blau, W ;
Barklie, RC .
PHYSICAL REVIEW B, 1998, 58 (12) :R7492-R7495
[8]   ALIGNED CARBON NANOTUBE FILMS - PRODUCTION AND OPTICAL AND ELECTRONIC-PROPERTIES [J].
DEHEER, WA ;
BACSA, WS ;
CHATELAIN, A ;
GERFIN, T ;
HUMPHREYBAKER, R ;
FORRO, L ;
UGARTE, D .
SCIENCE, 1995, 268 (5212) :845-847
[9]   Electrical conductivity of individual carbon nanotubes [J].
Ebbesen, TW ;
Lezec, HJ ;
Hiura, H ;
Bennett, JW ;
Ghaemi, HF ;
Thio, T .
NATURE, 1996, 382 (6586) :54-56
[10]   Metallic resistivity in crystalline ropes of single-wall carbon nanotubes [J].
Fischer, JE ;
Dai, H ;
Thess, A ;
Lee, R ;
Hanjani, NM ;
Dehaas, DL ;
Smalley, RE .
PHYSICAL REVIEW B, 1997, 55 (08) :R4921-R4924