Carbene complexes of titanium group metals -: formation and reactivity

被引：34

作者：

Beckhaus, R ^{[1
]}

Santamaría, C ^{[1
]}

机构：

[1] Carl von Ossietzky Univ Oldenburg, Fachbereich Chem, D-26111 Oldenburg, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 617卷 / 01期

关键词：

carbene complexes; titanium group metals; cycoladdition reactions;

D O I：

10.1016/S0022-328X(00)00710-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The principles in the formation of carbene complexes of titanium group metals are summarized. Characteristic examples of isolated as well as carbene complexes as intermediates are given. Selected structures and reactivity patterns are discussed. Starting from the Tebbe-type chemistry, new aspects of carbene complexes with only one or without cyclopentadienyl ligands are illustrated. In that direction, the formation of carbene complexes with N and O-donor ligands is described. Applications in co-ordination chemistry, organic syntheses and material sciences are summarized. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

收藏

页码：81 / 97

页数：17

相关论文

共 150 条

[61] Mechanistic studies of the thermolysis of tetraneopentyltitanium(IV) .1. Solution evidence that titanium alkylidenes activate saturated hydrocarbons [J].

Cheon, J ;

Rogers, DM ;

Girolami, GS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (29) :6804-6813

[62] Mechanistic studies of the thermolysis of tetraneopentyltitanium(IV) .2. Solid state and ultra-high-vacuum studies of the chemical vapor deposition of TiC films [J].

Cheon, J ;

Dubois, LH ;

Girolami, GS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (29) :6814-6820

[63] HALOGENFREIE METHYL-VERBINDUNGEN DES TITANS UND CHROMS [J].

CLAUSS, K ;

BEERMANN, C .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1959, 71 (19) :627-627

[64]

CLAUSS K, 1962, LIEBIGS ANN CHEM, V654, P8

[65] THEORETICAL INVESTIGATIONS OF OLEFIN METATHESIS CATALYSTS [J].

CUNDARI, TR ;

GORDON, MS .

ORGANOMETALLICS, 1992, 11 (01) :55-63

[66] HIGH-VALENT TRANSITION-METAL ALKYLIDENE COMPLEXES - EFFECT OF LIGAND AND SUBSTITUENT MODIFICATION [J].

CUNDARI, TR ;

GORDON, MS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (02) :539-548

[67] PRINCIPAL RESONANCE CONTRIBUTORS TO HIGH-VALENT, TRANSITION-METAL ALKYLIDENE COMPLEXES [J].

CUNDARI, TR ;

GORDON, MS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (14) :5231-5243

[68] A LI2TI2-SUBSTITUTED ACETYLENE FORMED FROM ETHYLENE BY REACTION WITH (MESO-OCTAETHYL-PORPHYRINOGEN)TITANIUM [J].

DEANGELIS, S ;

SOLARI, E ;

FLORIANI, C ;

CHIESIVILLA, A ;

RIZZOLI, C .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (10) :1092-1094

[69]

DEANGELIS S, 1995, ANGEW CHEM, V107, P1200

[70] SYNTHESIS OF ALLENYLKETENIMINES VIA TITANOCENE VINYLIDENE COMPLEXES [J].

DENNEHY, RD ;

WHITBY, RJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (01) :35-36

← 2 3 4 5 6 7 8 9 10 11 →