Optical fiber sensor based on lutetium bisphthalocyanine for the detection of gases using standard telecommunication wavelengths

被引:66
作者
Bariáin, C
Matías, IR [1 ]
Fernández-Valdivielso, C
Arregui, FJ
Rodríguez-Méndez, ML
de Saja, JA
机构
[1] Univ Publ Navarra, Dept Ingn Elect & Elect, E-31006 Pamplona, Spain
[2] Univ Valladolid, ETSII, Dept Quim Inorgan, E-47011 Valladolid, Spain
[3] Univ Valladolid, Fac Ciencias, Dept Fis Mat Condensada, E-47011 Valladolid, Spain
关键词
fiber optic gas sensor; lutetium bisphthalocyanine films; Langmuir-Blodgett technique; standard telecommunication windows;
D O I
10.1016/S0925-4005(03)00204-1
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this work, a vapochromic material, the lutetium bisphthalocyanine (LuPc2), whose refractive index changes in the presence of organic compound vapors such as ethanol, hexanal, n-butyl acetate, acetic acid, etc., has been used in combination with an optical fiber to fabricate an optical fiber volatile organic compound (VOC) sensor. The behavior of the sensor has been studied for the 1310 nm wavelength in the telecommunication window, with the associated advantages that this fact implies. In addition, different concentrations of volatile organic compound vapors have been tested. For instance, changes up to 10 dB in the reflected optical power have been detected for a 88 mmol/l concentration of acetic acid. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:153 / 158
页数:6
相关论文
共 23 条
[1]   Optical fiber humidity sensor using a nano Fabry-Perot cavity formed by the ionic self-assembly method [J].
Arregui, FJ ;
Liu, YJ ;
Matias, IR ;
Claus, RO .
SENSORS AND ACTUATORS B-CHEMICAL, 1999, 59 (01) :54-59
[2]  
Arregui FJ, 2000, IEICE T ELECTRON, VE83C, P360
[3]   Detection of volatile organic compound vapors by using a vapochromic material on a tapered optical fiber [J].
Bariáin, C ;
Matías, IR ;
Romeo, I ;
Garrido, J ;
Laguna, M .
APPLIED PHYSICS LETTERS, 2000, 77 (15) :2274-2276
[4]   Experimental results towards development of humidity sensors by using a hygroscopic material on biconically tapered optical fibre [J].
Bariain, C ;
Matias, IR ;
Arregui, FJ ;
Lopez-Amo, M .
OPTICAL AND FIBER OPTIC SENSOR SYSTEMS, 1998, 3555 :95-105
[5]   Behavioral experimental studies of a novel vapochromic material towards development of optical fiber organic compounds sensor [J].
Bariáin, C ;
Matías, IR ;
Romeo, I ;
Garrido, J ;
Laguna, M .
SENSORS AND ACTUATORS B-CHEMICAL, 2001, 76 (1-3) :25-31
[6]   Optical fiber humidity sensor based on a tapered fiber coated with agarose gel [J].
Bariáin, C ;
Matías, IR ;
Arregui, FJ ;
López-Amo, M .
SENSORS AND ACTUATORS B-CHEMICAL, 2000, 69 (1-2) :127-131
[7]   Gas sensitivity measurements on NO2 sensors based on copper(II) tetrakis(n-butylaminocarbonyl)phthalocyanine LB films [J].
Capone, S ;
Mongelli, S ;
Rella, R ;
Siciliano, P ;
Valli, L .
LANGMUIR, 1999, 15 (05) :1748-1753
[8]   SURFACE-ENHANCED RAMAN-SPECTRA AND GAS CHEMISORPTION OF LANGMUIR-BLODGETT LAYERS OF LUTETIUM AND YTTERBIUM DIPHTHALOCYANINES [J].
CLAVIJO, RE ;
BATTISTI, D ;
AROCA, R ;
KOVACS, GJ ;
JENNINGS, CA .
LANGMUIR, 1992, 8 (01) :113-117
[9]   Langmuir-Blodgett films of bis(octakispropyloxy) samarium bisphthalocyanine.: Spectroscopic and gas-sensing properties [J].
Gorbunova, Y ;
Rodríguez-Méndez, ML ;
Kalashnikova, IP ;
Tomilova, LG ;
de Saja, JA .
LANGMUIR, 2001, 17 (16) :5004-5010
[10]   Array of sensors based on lanthanide bisphtahlocyanine Langmuir-Blodgett films for the detection of olive oil aroma [J].
Gutierrez, N ;
Rodríguez-Méndez, ML ;
de Saja, JA .
SENSORS AND ACTUATORS B-CHEMICAL, 2001, 77 (1-2) :437-442