Formation of ZnMn2O4 Ball-in-Ball Hollow Microspheres as a High-Performance Anode for Lithium-Ion Batteries

被引:621
作者
Zhang, Genqiang [1 ,2 ]
Yu, Le [2 ]
Wu, Hao Bin [2 ]
Hoster, Harry E. [1 ]
Lou, Xiong Wen [1 ,2 ]
机构
[1] TUM CREATE Ctr Electromobil, Singapore 637459, Singapore
[2] Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637457, Singapore
基金
新加坡国家研究基金会;
关键词
STORAGE PROPERTIES; PRECURSOR ROUTE; SPHERES; CAPACITY; CELLS; FABRICATION; NANOWIRES;
D O I
10.1002/adma.201201779
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Novel ZnMn 2O 4 ball-in-ball hollow microspheres are fabricated by a facile two-step method involving the solution synthesis of ZnMn-glycolate hollow microspheres and subsequent thermal annealing in air. When evaluated as an anode material for lithium-ion batteries, these ZnMn 2O 4 ball-in-ball hollow microspheres show significantly enhanced electrochemical performance with high capacity, excellent cycling stability and good rate capability. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:4609 / 4613
页数:5
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