The Heck-type arylation of allylic alcohols with arenediazonium salts

被引：59

作者：

Masllorens, J

Bouquillon, S

Roglans, A

Hénin, F

Muzart, J

机构：

[1] Univ Reims, CNRS, Unite Mixte Rech React Select & Applicat, F-51687 Reims, France

[2] Univ Girona, Dept Chem, Girona 17071, Spain

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2005年 / 690卷 / 16期

关键词：

arylation; palladium; allylic alcohols; ketones; acetals; arenediazonium salts;

D O I：

10.1016/j.jorganchem.2005.05.020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Heck coupling of ArN2BF4 With secondary allylic alcohols, carried out in methanol using Pd(dba)(2) as catalyst without extra ligands and base, leads to the corresponding beta-arylated carbonyl compounds. Such conditions afford arylated acetals from primary allylic alcohols. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：3822 / 3826

页数：5

共 44 条

[41] Probing the stereoselectivity of the Heck arylation of endocyclic enecarbarnates with diazonium salts.: Concise syntheses of (2S,5R)-phenylproline methyl ester and Schramm's C-azanucleoside [J].