Transfer hydrogenation reduction of acetophenone catalyzed by Ru(II) and Rh(I) complexes with ligands derived from (1R,2R)-cyclohexane-1,2-diamine

被引：12

作者：

Cortez, NA ^{[1
]}

Flores-López, CZ ^{[1
]}

Rodríguez-Apodaca, R ^{[1
]}

Flores-López, LZ ^{[1
]}

Parra-Hake, M ^{[1
]}

Somanathan, R ^{[1
]}

机构：

[1] Inst Tecnol Tijuana, Ctr Graduados & Invest, Apartado Postal 11000, Tijuana, BC, Mexico

来源：

ARKIVOC | 2005年

关键词：

catalytic transfer hydrogenation; acetophenone reduction; Ru(II); Rh(I); chiral ligands; cyclohexane-1,2-diamine;

D O I：

10.3998/ark.5550190.0006.613

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A number of bidenate and tridentate ligands were synthesized from chiral mono sulfonamides, which were derived from cyclohexane-1,2-diamine. These ligands were tested with Ru(II) and Rh(I) for catalytic activity in the transfer hydrogenation reaction of ketone.

引用

页码：162 / 171

页数：10

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