PGSE NMR studies on RAPTA derivatives:: Evidence for the formation of H-bonded dicationic species

被引：28

作者：

Bolano, Sandra ^{[2
]}

Ciancaleoni, Gianluca ^{[1
]}

Bravo, Jorge ^{[2
]}

Gonsalvi, Luca ^{[3
]}

Macchioni, Alceo ^{[1
]}

Peruzzini, Maurizio ^{[3
]}

机构：

[1] Univ Perugia, Dipartimento Chim, I-06123 Perugia, Italy

[2] Univ Vigo, Fac Quim, Dept Quim Inorgan, Vigo 36310, Spain

[3] CNR ICCOM, I-50019 Sesto Fiorentino, FI, Italy

来源：

ORGANOMETALLICS | 2008年 / 27卷 / 07期

关键词：

D O I：

10.1021/om701131s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The self-aggregation tendency of RAPTA complexes {[Ru(eta(6)-p-cymene){PTA(-R)}Cl-2]X, R = H (1BPh(4) and 1PF(6)) and Me (2BPh(4) and 2OTf), and [Ru(eta(6)-p-cymene)(PTA)(2)Cl]X (3BPh(4) and 3BF(4))} in acetone-d(6) was investigated by means of diffusion NMR spectroscopy. On increasing the concentration, the protonated species (1X) undergoes intercationic self-aggregation driven by hydrogen bonding that leads to the formation of 1(2)(2+) dications and a small amount of 1(2)X(+) ion triples.

引用

页码：1649 / 1652

页数：4

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