Combining diffusion NMR and conductometric measurements to evaluate the hydrodynamic volume of ions and ion pairs

被引:26
作者
Ciancaleoni, Gianluca [1 ]
Zuccaccia, Cristiano [1 ]
Zuccaccia, Daniele [1 ]
Macchioni, Alceo [1 ]
机构
[1] Univ Perugia, Dipartimento Chim, I-06123 Perugia, Italy
关键词
D O I
10.1021/om700415f
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A simple methodology for rapidly and accurately determining the hydrodynamic volume of single ions and ion pairs, based on the combination of information derived from diffusion NMR spectroscopy and conductometry, is proposed.
引用
收藏
页码:3624 / 3626
页数:3
相关论文
共 42 条
[1]   Ionic conduction and self-diffusion near infinitesimal concentration in lithium salt-organic solvent electrolytes [J].
Aihara, Y ;
Sugimoto, K ;
Price, WS ;
Hayamizu, K .
JOURNAL OF CHEMICAL PHYSICS, 2000, 113 (05) :1981-1991
[2]   NMR techniques for the investigation of solvation phenomena and non-covalent interactions [J].
Bagno, A ;
Rastrelli, F ;
Saielli, G .
PROGRESS IN NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY, 2005, 47 (1-2) :41-93
[3]   Transition-metal receptor systems for the selective recognition and sensing of anionic guest species [J].
Beer, PD .
ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (02) :71-80
[4]  
Beer PD, 2001, ANGEW CHEM INT EDIT, V40, P486, DOI 10.1002/1521-3773(20010202)40:3<486::AID-ANIE486>3.3.CO
[5]  
2-G
[6]   PROPERTIES AND STRUCTURES OF ELECTROLYTE-SOLUTIONS FOR LITHIUM BATTERIES [J].
BLOMGREN, GE .
JOURNAL OF POWER SOURCES, 1985, 14 (1-3) :39-44
[7]   Intermolecular interaction as investigated by NOE and diffusion studies [J].
Brand, T ;
Cabrita, EJ ;
Berger, S .
PROGRESS IN NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY, 2005, 46 (04) :159-196
[8]   DIFFUSION OF CROWN ETHERS IN ALCOHOLS [J].
CHEN, HC ;
CHEN, SH .
JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (21) :5118-5121
[9]   Self-aggregation of amino-acidate half-sandwich ruthenium(II) complexes in solution: From monomers to nanoaggregates [J].
Ciancaleoni, Gianluca ;
Di Maio, Ilona ;
Zuccaccia, Daniele ;
Macchioni, Alceo .
ORGANOMETALLICS, 2007, 26 (03) :489-496
[10]   Diffusion NMR spectroscopy in supramolecular and combinatorial chemistry: An old parameter - New insights [J].
Cohen, Y ;
Avram, L ;
Frish, L .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (04) :520-554