Intermolecular interaction as investigated by NOE and diffusion studies

被引:237
作者
Brand, T
Cabrita, EJ
Berger, S
机构
[1] Univ Leipzig, Inst Analyt Chem, D-04103 Leipzig, Germany
[2] Univ Nova Lisboa, REQUIMTE, CQFB, Dept Quim,Fac Ciencias & Tecnol, P-2829516 Caparica, Portugal
关键词
D O I
10.1016/j.pnmrs.2005.04.003
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 [物理化学]; 081704 [应用化学];
摘要
The phenomena of intermolecular interaction was investigated. The study of intermolecular interaction is of fundamental significance for the understanding and rationalization of a number of biocatalytic mechanisms. Intermolecular interactions directly affect the reactivity of a biomolecule and can often be related to the observed selectivity of biocatalytic processes. Spin-echo NMR experiments have become a valuable tool for the study of intermolecular interaction.
引用
收藏
页码:159 / 196
页数:38
相关论文
共 206 条
[1]
ABRAHAM A, 1961, PRINCIPLES NUCL MAGN
[2]
Modified, pulse field gradient-enhanced inverse-detected HOESY pulse sequence for reduction of t1 spectral artifacts [J].
Alam, TM ;
Pedrotty, DM ;
Boyle, TJ .
MAGNETIC RESONANCE IN CHEMISTRY, 2002, 40 (05) :361-365
[3]
ASSOCIATION OF BIOMOLECULAR SYSTEMS VIA PULSED-FIELD GRADIENT NMR SELF-DIFFUSION MEASUREMENTS [J].
ALTIERI, AS ;
HINTON, DP ;
BYRD, RA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (28) :7566-7567
[4]
The pH-dependence of preferential solvation as studied by intermolecular homo- and heteronuclear NOE measurements of adenosine in water-trifluoroethanol mixtures [J].
Angulo, M ;
Berger, S .
ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2004, 378 (06) :1555-1560
[5]
Site-specific solvation determined by intermolecular nuclear Overhauser effect-measurements and molecular dynamics [J].
Angulo, M ;
Hawat, C ;
Hofmann, HJ ;
Berger, S .
ORGANIC & BIOMOLECULAR CHEMISTRY, 2003, 1 (06) :1049-1052
[6]
Using pulsed gradient spin echo NMR for chemical mixture analysis: How to obtain optimum results [J].
Antalek, B .
CONCEPTS IN MAGNETIC RESONANCE, 2002, 14 (04) :225-258
[7]
Spontaneous formation of hexameric resorcinarene capsule in chloroform solution as detected by diffusion NMR [J].
Avram, L ;
Cohen, Y .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (51) :15148-15149
[8]
The role of water molecules in a resorcinarene capsule as probed by NMR diffusion measurements [J].
Avram, L ;
Cohen, Y .
ORGANIC LETTERS, 2002, 4 (24) :4365-4368
[9]
Complexation in pseudorotaxanes based on α-cyclodextrin and different α,ω-diaminoalkanes by NMR diffusion measurements [J].
Avram, L ;
Cohen, Y .
JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (08) :2639-2644
[10]
Activation of dimethyl zirconocene by methylaluminoxane (MAO) -: Size estimate for Me-MAO- anions by pulsed field-gradient NMR [J].
Babushkin, DE ;
Brintzinger, HH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (43) :12869-12873