Equipment for combinatorial electrochemical polymerization and high-throughput investigation of electrical properties of the synthesized polymers

被引:29
作者
Kulikov, V [1 ]
Mirsky, VM [1 ]
机构
[1] Univ Regensburg, Inst Analyt Chem Chemo & Biosensors, D-93040 Regensburg, Germany
关键词
electropolymerization; chemical sensors; biological sensors; organic semiconductors; combinatorial approach; high-throughput screening;
D O I
10.1088/0957-0233/15/1/007
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The first automated system for combinatorial synthesis and high throughput investigation of electrical properties of conductive polymers is described. The equipment provides a polymerization of defined mixtures of monomers into a thin layer on the addressed electrodes of an electrode array followed by measurements of current-voltage characteristics. The electrodes have an interdigital configuration, specially designed for four-point measurements. A programmed addition of gases or liquids provides automated investigation of the influence of different substances on the synthesized polymers. The results of an experimental test of the system are presented. This equipment can be used for synthesis and electrical characterization of conductive polymers and multilayer polymer structures, for development of chemical sensors, organic electronic devices and other thin film functional structures.
引用
收藏
页码:49 / 54
页数:6
相关论文
共 16 条
[1]   Cross-reactive chemical sensor arrays [J].
Albert, KJ ;
Lewis, NS ;
Schauer, CL ;
Sotzing, GA ;
Stitzel, SE ;
Vaid, TP ;
Walt, DR .
CHEMICAL REVIEWS, 2000, 100 (07) :2595-2626
[2]  
[Anonymous], REV MOL BIOTECHNOL, DOI DOI 10.1016/S1389-0352(01)00058-7
[3]   THE APPLICATION OF CONDUCTING POLYMERS IN BIOSENSORS [J].
BARTLETT, PN ;
BIRKIN, PR .
SYNTHETIC METALS, 1993, 61 (1-2) :15-21
[4]  
Bernius MT, 2000, ADV MATER, V12, P1737, DOI 10.1002/1521-4095(200012)12:23<1737::AID-ADMA1737>3.0.CO
[5]  
2-N
[6]   Surfaces and interfaces in polymer-based electronics [J].
Fahlman, M ;
Salaneck, WR .
SURFACE SCIENCE, 2002, 500 (1-3) :904-922
[7]   Application of conducting polymers to biosensors [J].
Gerard, M ;
Chaubey, A ;
Malhotra, BD .
BIOSENSORS & BIOELECTRONICS, 2002, 17 (05) :345-359
[8]   Investigation of contact and bulk resistance of conducting polymers by simultaneous two- and four-point technique [J].
Hao, QL ;
Kulikov, V ;
Mirsky, VA .
SENSORS AND ACTUATORS B-CHEMICAL, 2003, 94 (03) :352-357
[9]   Electroconducting polymers for the construction of DNA or peptide arrays on silicon chips [J].
Livache, T ;
Bazin, H ;
Caillat, P ;
Roget, A .
BIOSENSORS & BIOELECTRONICS, 1998, 13 (06) :629-634
[10]   Conjugated polymer-based chemical sensors [J].
McQuade, DT ;
Pullen, AE ;
Swager, TM .
CHEMICAL REVIEWS, 2000, 100 (07) :2537-2574