Oximate-substituted zirconium alkoxides

被引：15

作者：

Baumann, Stefan O. ^{[1
]}

Puchberger, Michael ^{[1
]}

Schubert, Ulrich ^{[1
]}

机构：

[1] Vienna Univ Technol, Inst Mat Chem, A-1060 Vienna, Austria

来源：

DALTON TRANSACTIONS | 2011年 / 40卷 / 06期

基金：

奥地利科学基金会;

关键词：

TITANIUM ALKOXIDES; STRUCTURAL CHEMISTRY; COMPLEXES; LIGANDS; DERIVATIVES; CLUSTERS; BUTOXIDE;

D O I：

10.1039/c0dt00384k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of acetoxime, ethyl methyl ketoxime or cyclohexanone oxime with zirconium iso-propoxide gave dimeric alkoxo oximate derivatives [Zr(OiPr)(oximate)(3)](2). The oximate ligands are side-on coordinated and the alkoxo groups bridge the two metal centres. NMR spectroscopy revealed dynamic behaviour of the compounds in solution. When exposing a reaction mixture of zirconium butoxide and cyclohexanone oxime to ambient moisture, the oxo-alkoxo derivative Zr4O(OBu)(8)(ON=C6H10)(6) was obtained.

引用

页码：1401 / 1406

页数：6

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