Synthesis of electron-poor hexa-peri-hexabenzocoronenes

被引:40
作者
Jones, David J. [1 ]
Purushothaman, Balaji [1 ]
Ji, Shaomin [1 ]
Holmes, Andrew B. [1 ]
Wong, Wallace W. H. [1 ]
机构
[1] Univ Melbourne, Sch Chem, Inst Bio21, Parkville, Vic 3010, Australia
基金
澳大利亚研究理事会;
关键词
FIELD-EFFECT TRANSISTORS; SCHOLL REACTION; ORGANIC ELECTRONICS; FACILE SYNTHESIS; OXIDANT; DDQ;
D O I
10.1039/c2cc33892k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The oxidative cyclodehydrogenation of electron-poor arenes was achieved using DDQ-CF3SO3H resulting in hexa-peri-hexabenzocoronenes with electron withdrawing Br, F and CF3 groups. This method will lead to their expansion into a new class of electron transport materials.
引用
收藏
页码:8066 / 8068
页数:3
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