Effect of diffusion on ion beam-synthesized PbS nanocrystals

被引:7
作者
de Lamaestre, RE [1 ]
Bernas, H
Jomard, F
机构
[1] Univ Paris 11, CNRS, CSNSM, F-91405 Orsay, France
[2] Fontainbleau Res Ctr, Corning SA, F-77210 Avon, France
[3] CNRS, LPSB, F-92195 Meudon, France
关键词
PbS; nanocrystals; ion implantation; SIMS; TEM;
D O I
10.1016/j.nimb.2003.11.067
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
Combining secondary ion mass spectroscopy (SIMS) and transmission electron microscopy (TEM), we show that nucleation of PbS nanocrystals formed via co-implantation in pure silica is critically dependent on the post-implant diffusion properties of Pb and S. Upon annealing, implanted Pb diffuses classically whereas only a few percent of the implanted S diffuses significantly. After annealing at 850 degreesC/l h, the depth distribution of nanocrystals is no longer determined by the less concentrated element rather than the initial concentration profiles. Our results emphasize the role of glass chemistry in composite nanocrystal formation. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:402 / 406
页数:5
相关论文
共 12 条
[1]   Ion-beam synthesis and structural characterization of ZnS nanocrystals in SiO2 [J].
Bonafos, C ;
Garrido, B ;
Lopez, M ;
Romano-Rodriguez, A ;
Gonzalez-Varona, O ;
Perez-Rodriguez, A ;
Morante, JR .
APPLIED PHYSICS LETTERS, 1998, 72 (26) :3488-3490
[2]  
BORELLI NF, 1994, J NONCRYST SOLIDS, V180, P25
[3]   GROWTH OF CDSE NANOCRYSTALS IN ION-IMPLANTED SIO2-FILMS [J].
EKIMOV, A ;
GUREVICH, S ;
KUDRIAVTSEV, I ;
LUBLINSKAYA, O ;
MERKULOV, A ;
OSINSKII, A ;
VATNIK, M ;
GANDAIS, M ;
WANG, Y .
JOURNAL OF CRYSTAL GROWTH, 1995, 151 (1-2) :38-45
[4]  
Malyarevich AM, 2001, PHYS STATUS SOLIDI B, V224, P253, DOI 10.1002/1521-3951(200103)224:1<253::AID-PSSB253>3.0.CO
[5]  
2-#
[6]   Passively Q-switched Ho3+:Y3Al5O12 laser using a PbSe-doped glass [J].
Malyarevich, AM ;
Prokoshin, PV ;
Demchuk, MI ;
Yumashev, KV ;
Lipovskii, AA .
APPLIED PHYSICS LETTERS, 2001, 78 (05) :572-573
[7]   Microstructure of sulfide nanocrystals formed by ion-implantation [J].
Meldrum, A ;
White, CW ;
Boatner, LA ;
Anderson, IM ;
Zuhr, RA ;
Sonder, E ;
Budai, JD ;
Henderson, DO .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1999, 148 (1-4) :957-963
[8]   Diode-pumped erbium-ytterbium-glass laser passively Q-switched with a PbS semiconductor quantum-dot doped glass [J].
Philipps, JF ;
Töpfer, T ;
Ebendorff-Heidepriem, H ;
Ehrt, D ;
Sauerbrey, R ;
Borrelli, NF .
APPLIED PHYSICS B-LASERS AND OPTICS, 2001, 72 (02) :175-178
[9]  
VOLF MB, 1984, CHEM APPROACH GLASS, P524
[10]   Encapsulated nanocrystals and quantum dots formed by ion beam synthesis [J].
White, CW ;
Budai, JD ;
Withrow, SP ;
Zhu, JG ;
Pennycook, SJ ;
Zuhr, RA ;
Hembree, DM ;
Henderson, DO ;
Magruder, RH ;
Yacaman, MJ ;
Mondragon, G ;
Prawer, S .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1997, 127 :545-552