(CN3H6)2•Zn(HPO3)2:: An open-framework zincophosphite built up from polyhedral 12-rings

被引：89

作者：

Harrison, WTA ^{[1
]}

Phillips, MLF

Nenoff, TM

机构：

[1] Univ Aberdeen, Dept Chem, Aberdeen AB24 3UE, Scotland

[2] Sandia Natl Labs, Albuquerque, NM 87185 USA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 17期

关键词：

D O I：

10.1039/b102007m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The solution-mediated synthesis and single crystal structure of (CN3H6)(2). Zn(HPO3)(2) are reported. This phase is built up from a three-dimensional framework of vertex-linked ZnO4 and HPO3 building units encapsulating the extraframework guanidinium cations. The structure is stabilised by template-to-framework hydrogen bonding. The inorganic framework contains polyhedral 12-rings and shows a surprising similarity to those of some known organically-templated zinc phosphates.

引用

页码：2459 / 2461

页数：3

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