Direct arylation reactions catalyzed by Pd(OH)2/C:: Evidence for a soluble palladium catalyst

被引：293

作者：

Parisien, M ^{[1
]}

Valette, D ^{[1
]}

Fagnou, K ^{[1
]}

机构：

[1] Univ Ottawa, Ctr Catalysis Res & Innovat, Dept Chem, Ottawa, ON K1N 6N5, Canada

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 70卷 / 19期

关键词：

D O I：

10.1021/jo051039v

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium hydroxide on carbon (Pearlman's catalyst) effectively catalyzes direct arylation reactions of aryl iodides and bromides, providing excellent arylation-to-hydrodehalogenation ratios (> 30:1) with broad scope for both intra- and intermolecular arylation processes. Studies aimed at determining the nature of the active catalyst indicate that an active homogeneous palladium species is produced under the reaction conditions.

引用

页码：7578 / 7584

页数：7