Synthesis and molecular structure of trans-2-allyl-6-phenyl-1,2,3,6-tetrahydropyridine hydrochloride

被引：2

作者：

Bubnov, YN ^{[1
]}

Klimkina, EV ^{[1
]}

Dekaprilevich, MO ^{[1
]}

Struchkov, YT ^{[1
]}

机构：

[1] AN NESMEYANOV ORGANOELEMENT CPDS INST,MOSCOW 117813,RUSSIA

来源：

RUSSIAN CHEMICAL BULLETIN | 1996年 / 45卷 / 11期

关键词：

allylboronation; pyridine; 1,2-addition; phenyllithium; triallylborane; trans-2-allyl-6-phenyl-1,2,3,6-tetrahydropyridine; X-ray structural analysis;

D O I：

10.1007/BF01431124

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

When treated with triallylborane and MeOH, the product of the 1,2-addition of PhLi to pyridine transforms to trans-2-allyl-6-phenyl-1,2,3,6-tetrahydropyridine. The structure of its hydrochloride was established by X-ray structural analysis.

引用

页码：2595 / 2597

页数：3

共 8 条

[1] REDUCTIVE 2,6-TRANS-DIALLYLATION OF PYRIDINE BY TRIALLYLBORANE [J].

BUBNOV, YN ;

SHAGOVA, EA ;

EVCHENKO, SV ;

IGNATENKO, AV ;

GRIDNEV, ID .

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1991, 40 (11) :2315-2315

[2] SYNTHESIS AND MOLECULAR-STRUCTURE OF 3-BROMO-TRANS-2,6-DIALLYL-DELTA(3)-PIPERIDEINE HYDROCHLORIDE [J].

BUBNOV, YN ;

SHAGOVA, EA ;

EVCHENKO, SV ;

DEKAPRILEVICH, MO ;

STRUCHKOV, YT .

RUSSIAN CHEMICAL BULLETIN, 1994, 43 (04) :657-659

[3] REDUCTIVE TRANS-2,6-DIALLYLATION OF PYRIDINES WITH ALLYLBORANES - SYNTHESIS OF TRANS-2,6-DIALLYL-1,2,5,6-TETRAHYDROPYRIDINES AND CIS-2,6-DIALLYL-1,2,5,6-TETRAHYDROPYRIDINES AND THEIR DEUTERATED DERIVATIVES [J].

BUBNOV, YN ;

SHAGOVA, EA ;

EVCHENKO, SV ;

IGNATENKO, AV .

RUSSIAN CHEMICAL BULLETIN, 1994, 43 (04) :645-656

[4] ALLYLBORANES - REDUCTIVE MONOALLYLATION AND TRANS-DIALLYLATION OF AROMATIC NITROGEN-CONTAINING HETEROCYCLIC-COMPOUNDS [J].

BUBNOV, YN .

RUSSIAN CHEMICAL BULLETIN, 1995, 44 (07) :1156-1170

[5] REDUCTIVE MONO-ALPHA AND TRANS-ALPHA, ALPHA'-DIALLYLATION OF AROMATIC NITROGEN-HETEROCYCLES BY ALLYLBORANES [J].

BUBNOV, YN .

PURE AND APPLIED CHEMISTRY, 1994, 66 (02) :235-244

[6]

BUBNOV YN, 1996, TETRAHEDRON LETT, V37, P1337

[7]

EVCHENKO SV, 1994, THESIS RUSSIAN ACAD

[8]

ROBINSON W, 1988, CRYSTALLOGRAPHIC COM, P366

← 1 →