A modular and efficient synthesis of functional titanocenes

被引：56

作者：

Gansäuer, A

Franke, D

Lauterbach, T

Nieger, M

机构：

[1] Univ Bonn, Kekule Inst Organ Chem & Biochem, D-53121 Bonn, Germany

[2] Univ Bonn, Inst Anorgan Chem, D-53121 Bonn, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 33期

关键词：

D O I：

10.1021/ja054185r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A modular synthesis of functional titanocenes featuring building blocks is described. The approach allows straightforward access to large numbers of structurally diverse titanocenes that are pertinent for catalysis, structural studies, and bioinorganic chemistry. Among the functional groups introduced are amino acids, sugars, and fluorescence labels that are attached to the cyclopentadienyl ligand as esters and amides. Copyright © 2005 American Chemical Society.

引用

页码：11622 / 11623

页数：2

共 21 条

[11]

Jutzi P, 1998, EUR J INORG CHEM, P663

[12]

KOPFMAIER P, 1987, CHEM REV, V87, P1137

[13]

Marek I., 2002, TITANIUM ZIRCONIUM O

[14] The isocyanate route to cyclopentadienyl-carboxamide- and cyclopentadienyl-amino ester-substituted metallocene complexes [J].