Synthesis, structures, and catalytic reactions of ring-substituted titanium(IV) complexes

被引：165

作者：

Qian, YL ^{[1
]}

Huang, JL ^{[1
]}

Bala, MD ^{[1
]}

Lian, B ^{[1
]}

Zhang, H ^{[1
]}

机构：

[1] E China Univ Sci & Technol, Organ Chem Lab, Shanghai 200237, Peoples R China

来源：

CHEMICAL REVIEWS | 2003年 / 103卷 / 07期

关键词：

D O I：

10.1021/cr020002x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A study was performed on the synthesis, structures and catalytic reactions of ring-substituted titanium(IV) complexes. The synthetic methodologies to various classes of titanocenes based on the nature of ring substitution were reviewed. It was shown that the half-sandwich titanocenes and the constrained geometry linked-amido cyclopentadienyl(indenyl) titanium complexes remain the most active area of titanium research.

引用

页码：2633 / 2690

页数：58

共 366 条

[1] Synthesis and X-ray crystal structures of ansa-complexes of titanium, zirconium, and hafnium involving methylene-bis(indenyl) ligand [J].

Agarkov, AY ;

Izmer, VV ;

Riabov, AN ;

Kuz'mina, LG ;

Howard, JAK ;

Beletskaya, IP ;

Voskoboynikov, AZ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 619 (1-2) :280-286

[2] ELECTRONIC STRUCTURAL EFFECTS IN THE STRUCTURE OF TRICHLORO(ETA-5-ETHYLTETRAMETHYLCYCLOPENTADIENYL)TITANIUM(IV), TI(C11H17)CL3 [J].

ALCOCK, NW ;

TOOGOOD, GE ;

WALLBRIDGE, MGH .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1984, 40 (APR) :598-600

[3] Synthesis, characterization and polymerization potential of ansa-metallocene dichloride complexes of titanium, zirconium and hafnium containing a Si-N-Si bridging unit [J].

Alt, HG ;

Fottinger, K ;

Milius, W .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 564 (1-2) :109-114

[4] Bridged and unbridged substituted indenyl complexes of titanium and zirconium as catalysts for homogeneous and heterogeneous homo- and copolymerization of olefins [J].

Alt, HG ;

Weis, A ;

Reb, A ;

Ernst, R .

INORGANICA CHIMICA ACTA, 2003, 343 :253-274

[5] Effect of the nature of metallocene complexes of group IV metals on their performance in catalytic ethylene and propylene polymerization [J].

Alt, HG ;

Köppl, A .

CHEMICAL REVIEWS, 2000, 100 (04) :1205-1221

[6] ω-phenylalkyl substituted amido functionalized ansa half-sandwich complexes of titanium and zirconium and metallacycles thereof as catalyst precursors for homogeneous ethylene polymerization [J].

Alt, HG ;

Reb, A ;

Kundu, K .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 628 (02) :211-221

[7] Amido functionalized ansa half-sandwich dichloride complexes of titanium, zirconium and hafnium with alkyl and ω-alkenyl substituents as homogeneous and self-immobilizing catalyst precursors for ethylene polymerization [J].

Alt, HG ;

Reb, A ;

Milius, W ;

Weis, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 628 (02) :169-182

[8] The heterogenization of homogeneous metallocene catalysts for olefin polymerization [J].

Alt, HG .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (11) :1703-1709

[9] Synthesis, characterization and polymerization properties of bridged halfsandwich complexes of titanium, Zirconium and Hafnium -: The molecular structure of [C13H8-SiMe2-NtBu]ZrCl2 [J].

Alt, HG ;

Fottinger, K ;

Milius, W .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 572 (01) :21-30

[10] Alkyl complexes of group 4 metals-containing a tridentate-linked amido-cyclopentadienyl ligand: Synthesis, structure, and reactivity including ethylene polymerization catalysis [J].

Amor, F ;

Butt, A ;

du Plooy, KE ;

Spaniol, TP ;

Okuda, J .

ORGANOMETALLICS, 1998, 17 (26) :5836-5849

← 1 2 3 4 5 6 7 8 9 10 →