Synthesis, structures, and catalytic reactions of ring-substituted titanium(IV) complexes

被引:165
作者
Qian, YL [1 ]
Huang, JL [1 ]
Bala, MD [1 ]
Lian, B [1 ]
Zhang, H [1 ]
Zhang, H [1 ]
机构
[1] E China Univ Sci & Technol, Organ Chem Lab, Shanghai 200237, Peoples R China
关键词
D O I
10.1021/cr020002x
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A study was performed on the synthesis, structures and catalytic reactions of ring-substituted titanium(IV) complexes. The synthetic methodologies to various classes of titanocenes based on the nature of ring substitution were reviewed. It was shown that the half-sandwich titanocenes and the constrained geometry linked-amido cyclopentadienyl(indenyl) titanium complexes remain the most active area of titanium research.
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收藏
页码:2633 / 2690
页数:58
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共 366 条
[31]   New titanium and zirconium sandwich and half-sandwich complexes containing the C(5)Me(4)CH(2)CH(2)CH=CH2(Cp(=)) ligand [J].
Butakoff, KA ;
Lemenovskii, DA ;
Mountford, P ;
Kuzmina, LG ;
Churakov, AV .
POLYHEDRON, 1996, 15 (03) :489-499
[32]   Cyclopentadienylmetal complexes bearing pendant phosphorus, arsenic, and sulfur ligands [J].
Butenschön, H .
CHEMICAL REVIEWS, 2000, 100 (04) :1527-1564
[33]   Ring slippage in indenyl complexes: structure and bonding [J].
Calhorda, MJ ;
Veiros, LF .
COORDINATION CHEMISTRY REVIEWS, 1999, 185-6 :37-51
[34]   FULVALENE CYCLOPENTADIENYL TITANIUM AND ZIRCONIUM(III) AND ZIRCONIUM(IV) COMPLEXES - X-RAY CRYSTAL-STRUCTURE OF [(TI(ETA-5-C5H5)CL)2(MU-O)(MU-ETA-5-ETA-5-C10H8)] [J].
CANO, A ;
CUENCA, T ;
RODRIGUEZ, G ;
ROYO, P ;
CARDIN, C ;
WILCOCK, DJ .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 447 (01) :51-57
[35]   Application of amine elimination for the efficient preparation of electrophilic ansa-monocyclopentadienyl group 4 complexes containing an appended amido functionality. Structural characterization of [(C5H4) SiMe(2)(N-t-Bu)] ZrCl2 (NMe(2)H) [J].
Carpenetti, DW ;
Kloppenburg, L ;
Kupec, JT ;
Petersen, JL .
ORGANOMETALLICS, 1996, 15 (06) :1572-1581
[36]   Titanacyclobutane synthesis by radical alkylation of substituted allyl complexes. The use of electron-rich bis(2-piperidinoindenyl)titanocene(III) complexes to control allyl ligand reactivity [J].
Carter, CAG ;
McDonald, R ;
Stryker, JM .
ORGANOMETALLICS, 1999, 18 (05) :820-822
[37]   Density functional study on activation and ion-pair formation in group IV metallocene and related olefin polymerization catalyses [J].
Chan, MSW ;
Vanka, K ;
Pye, CC ;
Ziegler, T .
ORGANOMETALLICS, 1999, 18 (22) :4624-4636
[38]   Cocatalysts for metal-catalyzed olefin polymerization: Activators, activation processes, and structure-activity relationships [J].
Chen, EYX ;
Marks, TJ .
CHEMICAL REVIEWS, 2000, 100 (04) :1391-1434
[39]   ''Constrained geometry'' dialkyl catalysts. Efficient syntheses, C-H bond activation chemistry, monomer-dimer equilibration, and alpha-olefin polymerization catalysis [J].
Chen, YX ;
Marks, TJ .
ORGANOMETALLICS, 1997, 16 (16) :3649-3657
[40]   Organo-Lewis acids as cocatalysts in cationic metallocene polymerization catalysis. Unusual characteristics of sterically encumbered tris(perfluorobiphenyl)borane [J].
Chen, YX ;
Stern, CL ;
Yang, ST ;
Marks, TJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (49) :12451-12452