Controlled synthesis of nanocrystalline Li2MnSiO4 particles for high capacity cathode application in lithium-ion batteries

被引:100
作者
Kempaiah, Devaraju M. [1 ]
Rangappa, Dinesh [1 ]
Honma, Itaru [1 ]
机构
[1] Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Aoba Ku, Sendai, Miyagi 9808577, Japan
关键词
SOLVOTHERMAL SYNTHESIS; ELECTROCHEMICAL PERFORMANCE; LI2FESIO4; MICROSPHERES; LIFEPO4; MN;
D O I
10.1039/c2cc17234h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Monodispersed Li2MnSiO4 nanoparticles are synthesized via a supercritical solvothermal method at 300 degrees C for 5 min reaction time. The as-synthesized nanoparticles are free from impurities and have 15-20 nm diameter. After coating with conductive polymer, a discharge capacity of 313 mA h g(-1) is obtained for the first time because of nearly 2Li(+) reaction.
引用
收藏
页码:2698 / 2700
页数:3
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