Spin canting and metamagnetism in a 3D homometallic molecular material constructed by interpenetration of two kinds of cobalt(II)-coordination-polymer sheets

被引：299

作者：

Zeng, MH

Zhang, WX

Sun, XZ

Chen, XM ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China

[2] GuangXi Normal Univ, Res Inst Bioorgan Chem, Dept Chem & Chem Engn, Guilin 541004, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 20期

关键词：

cobalt; magnetic properties; metamagnets; N ligands; O ligands;

D O I：

10.1002/anie.200462463

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two different types of coordination sheets made up of CoII ions, 3-hydroxypicolinate, and 4,4′-bipyridine interpenetrate to form a unique molecular-based magnetic material (see picture). This material displays a low-field metamagnetic transition and spin-canted behavior. (Figure Presented) © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

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收藏

页码：3079 / 3082

页数：4

相关论文

共 44 条

[31] The first metamagnetic one-dimensional molecular material with nickel(II) and end-to-end azido bridges [J].

Mukherjee, PS ;

Dalai, S ;

Zangrando, E ;

Lloret, F ;

Chaudhuri, NR .

CHEMICAL COMMUNICATIONS, 2001, (16) :1444-1445

[32] Two-dimensional metamagnet composed of cyano-bridged CuII-WV bimetallic assembly [J].

Ohkoshi, S ;

Arimoto, Y ;

Hozumi, T ;

Seino, H ;

Mizobec, Y ;

Hashimoto, K .

CHEMICAL COMMUNICATIONS, 2003, (22) :2772-2773

[33]

Pereira C. L. M., 2004, ANGEW CHEM, V116, P974

[34] A CuIICoII metallacyclophane-based metamagnet with a corrugated brick-wall sheet architecture [J].

Pereira, CLM ;

Pedroso, EF ;

Stumpf, HO ;

Novak, MA ;

Ricard, L ;

Ruiz-García, R ;

Rivière, E ;

Journaux, Y .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (08) :956-958

[35] Coordination modes of 3-hydroxypicolinic acid:: synthesis and crystal structures of palladium(II), platinum(II) and rhenium(V) complexes [J].

Quintal, SMO ;

Nogueira, HIS ;

Félix, V ;

Drew, MGB .

NEW JOURNAL OF CHEMISTRY, 2000, 24 (07) :511-517

[36]

Renard J.-P., 1987, Organic and Inorganic Low-Dimensional Crystalline Materials. Proceedings of a NATO Advanced Research Workshop, P125

[37]

*SHELXTL, 2000, SHELXTL 6 10 BRUK AN

[38] A three-dimensional manganese(II) complex exhibiting ferrimagnetic and metamagnetic behaviors [J].

Wang, RH ;

Gao, EQ ;

Hong, MC ;

Gao, S ;

Luo, JH ;

Lin, ZZ ;

Han, L ;

Cao, R .

INORGANIC CHEMISTRY, 2003, 42 (18) :5486-5488

[39] Cu4{CH3C(OH)(PO3)2}2(C4H4N2)(H2O)4:: a novel, three-dimensional copper diphosphonate with metamagnetism [J].

Yin, P ;

Zheng, LM ;

Gao, S ;

Xin, XQ .

CHEMICAL COMMUNICATIONS, 2001, (22) :2346-2347

[40] Superstructural diversity in two dimensions: crystal engineering of laminated solids [J].

Zaworotko, MJ .

CHEMICAL COMMUNICATIONS, 2001, (01) :1-9

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