Two-dimensional metamagnet composed of cyano-bridged CuII-WV bimetallic assembly

被引：73

作者：

Ohkoshi, S

Arimoto, Y

Hozumi, T

Seino, H

Mizobec, Y

Hashimoto, K

机构：

[1] Univ Tokyo, Adv Sci & Technol Res Ctr, Meguro Ku, Tokyo 1538904, Japan

[2] JST, PRESTO, Kawaguchi, Saitama, Japan

[3] Univ Tokyo, Inst Ind Sci, Meguro Ku, Tokyo 1538505, Japan

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 22期

关键词：

D O I：

10.1039/b310456g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two-dimensional cyanide-bridged copper(II) octacyanotungstates(v), [{Cu(3-CNpy)(2)(H2O)}(2){Cu(3-CNpy)(2)(H2O)(2)}{W(CN)(8)}(2)] (3-CNpy = 3-cyanopyridine) (1) and [{Cu(4-CNpy)(2)}(2){Cu(4-CNpy)(2)(H2O)(2)}{W(CN)(8)}(2)].6H(2)O (4-CNpy = 4-cyanopyridine) (2), were prepared and these compounds exhibited metamagnetic behavior with Neel temperatures of 8.0 K (1) and 4.4 K (2).

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收藏

页码：2772 / 2773

页数：2

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