A Facile Route to Polymer Solar Cells with Optimum Morphology Readily Applicable to a Roll-to-Roll Process without Sacrificing High Device Performance

被引:130
作者
Park, Hui Joon
Kang, Myung-Gyu [1 ]
Ahn, Se Hyun [2 ]
Guo, L. Jay [1 ]
机构
[1] Univ Michigan, Dept Elect Engn & Comp Sci, Ann Arbor, MI 48109 USA
[2] Univ Michigan, Dept Mech Engn, Ann Arbor, MI 48109 USA
关键词
PHASE-SEPARATION; HIGH-THROUGHPUT; POLY(3-HEXYLTHIOPHENE); ORGANIZATION; EVOLUTION; BLENDS;
D O I
10.1002/adma.201000250
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new fabrication method for polymer solar cells that can produce optimized vertical distribution of components is reported. The favorable donor-acceptor morphology showing a well-organized photo-induced charge transporting pathway with fine nanodomains and high crystallinity is achieved. This process is also readily scalable to a large-area and High-speed roll-to-roll process without sacrificing high device performances, even without a PEDOT:PSS layer.
引用
收藏
页码:E247 / +
页数:8
相关论文
共 31 条
[21]   Compositional dependence of the performance of poly(p-phenylene vinylene):: Methanofullerene bulk-heterojunction solar cells [J].
Mihailetchi, VD ;
Koster, LJA ;
Blom, PWM ;
Melzer, C ;
de Boer, B ;
van Duren, JKJ ;
Janssen, RAJ .
ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (05) :795-801
[22]   Solar energy: A new day dawning?: Silicon Valley sunrise [J].
Morton, Oliver .
NATURE, 2006, 443 (7107) :19-22
[23]   High-throughput and etch-selective nanoimprinting and stamping based on fast-thermal-curing poly(dimethylsiloxane)s [J].
Pina-Hernandez, Carlos ;
Kim, Jin-Sung ;
Guo, L. Jay ;
Fu, Peng-Fei .
ADVANCED MATERIALS, 2007, 19 (09) :1222-+
[24]   PHOTOINDUCED ELECTRON-TRANSFER FROM A CONDUCTING POLYMER TO BUCKMINSTERFULLERENE [J].
SARICIFTCI, NS ;
SMILOWITZ, L ;
HEEGER, AJ ;
WUDL, F .
SCIENCE, 1992, 258 (5087) :1474-1476
[25]   Effect of self-organization in polymer/fullerene bulk heterojunctions on solar cell performance [J].
Shrotriya, Vishal ;
Yao, Yan ;
Li, Gang ;
Yang, Yang .
APPLIED PHYSICS LETTERS, 2006, 89 (06)
[26]   OPTICAL-ABSORPTION OF POLY(3-ALKYLTHIOPHENES) AT LOW-TEMPERATURES [J].
SUNDBERG, M ;
INGANAS, O ;
STAFSTROM, S ;
GUSTAFSSON, G ;
SJOGREN, B .
SOLID STATE COMMUNICATIONS, 1989, 71 (06) :435-439
[27]   Tuning the dimensions of C60-based needlelike crystals in blended thin films [J].
Swinnen, A ;
Haeldermans, I ;
vande Ven, M ;
D'Haen, J ;
Vanhoyland, G ;
Aresu, S ;
D'Olieslaeger, M ;
Manca, J .
ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (06) :760-765
[28]   Three-Dimensional Nanoscale Organization of Bulk Heterojunction Polymer Solar Cells [J].
van Bavel, Svetlana S. ;
Sourty, Erwan ;
de With, Gijsbertus ;
Loos, Joachim .
NANO LETTERS, 2009, 9 (02) :507-513
[29]   Vertical Phase Separation in Poly(3-hexylthiophene): Fullerene Derivative Blends and its Advantage for Inverted Structure Solar Cells [J].
Xu, Zheng ;
Chen, Li-Min ;
Yang, Guanwen ;
Huang, Chun-Hao ;
Hou, Jianhui ;
Wu, Yue ;
Li, Gang ;
Hsu, Chain-Shu ;
Yang, Yang .
ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (08) :1227-1234
[30]   Effect of solvent mixture on the nanoscale phase separation in polymer solar cells [J].
Yao, Yan ;
Hou, Jianhui ;
Xu, Zheng ;
Li, Gang ;
Yang, Yang .
ADVANCED FUNCTIONAL MATERIALS, 2008, 18 (12) :1783-1789