Mn(salen)-catalyzed enantioselective C-H amination

被引：136

作者：

Kohmura, Y ^{[1
]}

Katsuki, T ^{[1
]}

机构：

[1] Kyushu Univ 33, JST, CREST, Fac Sci,Dept Chem,Higashi Ku, Fukuoka 8128581, Japan

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 19期

关键词：

(salen)manganese(III) complex; asymmetric C-H amination; benzylic amination; allylic amination;

D O I：

10.1016/S0040-4039(01)00427-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A chiral 3.3',5,5'-tetrabromosubstituted (salen)manganese(III) complex was found to be an efficient catalyst for asymmetric Cn amination (up to 89% ee). In the reaction of cycloalkenes, allylic amination occurred in preference to aziridination, (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：3339 / 3342

页数：4

共 29 条

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