Charge-discharge mechanism of LiCoPO4 cathode for rechargeable lithium batteries

被引：26

作者：

Okada, S

Sawa, S

Uebou, Y

Egashira, M

Yamaki, J

Tabuchi, M

Kobayashi, H

Fukumi, K

Kageyama, H

机构：

[1] Kyushu Univ, Inst Mat Chem & Engn, Kasuga, Fukuoka 8168580, Japan

[2] Natl Inst Adv Ind Sci & Technol, Ikeda, Osaka 5638577, Japan

来源：

ELECTROCHEMISTRY | 2003年 / 71卷 / 12期

关键词：

cathode; olivine; LiCoPO4;

D O I：

10.5796/electrochemistry.71.1136

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The structure of ordered-olivine LiCoPO4 was identified by neutron diffraction measurements. A 4.8 V discharge profile was demonstrated using coin-type cells. XAFS and magnetic measurements indicated that the high-voltage plateau of Li1-xCoPO4 corresponds to the Co2+ /Co3+ redox reaction.

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收藏

页码：1136 / 1138

页数：3

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