A theory for the magnetic hyperfine interactions in the microwave spectrum of NO-HF

被引：14

作者：

Dennis, CR ^{[1
]}

Whitham, CJ ^{[1
]}

Howard, BJ ^{[1
]}

机构：

[1] Phys & Theoret Chem Lab, Oxford OX1 3QZ, England

来源：

JOURNAL OF CHEMICAL PHYSICS | 2001年 / 115卷 / 03期

关键词：

D O I：

10.1063/1.1377026

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A theory is presented for the fine and hyperfine interactions in the (2)Pi state open shell complexes like NO-HF containing remote magnetic nuclei. The nitrogen hyperfine Hamiltonian is based on the conventional Frosch and Foley treatment for diatomic radicals. An alternative treatment has been developed for the intermolecular hydrogen and fluorine magnetic hyperfine interactions based on a dipolar model for both electron spin and orbital magnetic moments. (C) 2001 American Institute of Physics.

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页码：1355 / 1366

页数：12

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