Libraries of bidentate phosphorus ligands; Synthesis strategies and application in catalysis

被引：90

作者：

Goudriaan, P. Elsbeth ^{[1
,4
]}

van Leeuwen, Piet W. N. M. ^{[2
,3
,4
]}

Birkholz, Mandy-Nicole ^{[1
,4
]}

Reek, Joost N. H. ^{[1
,4
]}

机构：

[1] Univ Amsterdam, NL-1012 WX Amsterdam, Netherlands

[2] Tech Univ Eindhoven, Eindhoven, Netherlands

[3] Inst Chem Res Catalonia ICIQ, Tarragona, Spain

[4] Vant Hoff Inst Mol Sci, NL-1018 WV Amsterdam, Netherlands

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2008年 / 19卷 / 19期

关键词：

ligand libraries; P ligands; chelates; supramolecular chemistry; combinatorial chemistry; asymmetric catalysis;

D O I：

10.1002/ejic.200800139

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Combinatorial chemistry in combination with high-throughput screening technologies is an important way of finding new successful catalyst systems. The design of ligand libraries of bidentate phosphorus ligands and the application of their transition-metal complexes in homogeneous (asymmetric) catalysis reactions will be described in this review. Till now three different approaches were developed to arrive at such libraries of bidentate phosphorus ligands: 1) modular synthesis of bidentate ligands 2) the solid support synthesis of bidentate ligands and 3) the self-assembly of ligand building blocks into bidentate ligands. The scope and limitations of these strategies will be discussed on the basis of a limited number of articles that dealt with the synthesis of at least 15 bidentate phosphorus ligands. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).

引用

页码：2939 / 2958

页数：20

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