Borato-cyclopentadienyl half-sandwich complexes.: Crystal structures of [NEt4][C5H5B(C6F5)3]•CH2Cl2 and [NEt4]2[{C5H4B(C6F5)3}Zr(μ-Cl)Cl2]2

被引：30

作者：

Lancaster, SJ ^{[1
]}

Thornton-Pett, M ^{[1
]}

Dawson, DM ^{[1
]}

Bochmann, M ^{[1
]}

机构：

[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 18期

关键词：

D O I：

10.1021/om980395j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cation exchange of [Li(THF)(4)](+)[C5H5B(C6F5)(3)](-) with [NEt4][BF4] gives the stable, ether-free salt [NEt4][C5H5B(C6F5)(3)], which reacts cleanly with Zr(NMe2)(4) to afford [NEt4][{C5H4B(C6F5)(3)}Zr(NMe2)(3)] in good yield. The triamide is readily converted into the crystallographically characterized dimeric trichloride [NEt4](2)[{C5H4B(C6F5)(3)}Zr(mu-Cl)Cl-2](2).

引用

页码：3829 / 3831

页数：3

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