An illustration of the limit of the metal organic framework's isoreticular principle using a semirigid tritopic linker obtained by "Click" chemistry

被引：57

作者：

Devic, Thomas ^{[1
]}

David, Olivier ^{[1
]}

Valls, Marion ^{[1
]}

Marrot, Jerome ^{[1
]}

Couty, Francois ^{[1
]}

Ferey, Gerard ^{[1
]}

机构：

[1] Univ Versailles, Inst Lavoisier, CNRS, UMR 8180, F-78035 Versailles, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 42期

关键词：

D O I：

10.1021/ja0744091

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new nitrogen-rich tricarboxylate linker was prepared by "click" chemistry and used for the preparation of a lanthanum-based open metal organic framework. This latter is built of inorganic 1-D rods connected through the tritopic linkers and illustrates one limit of the isoreticular principle, which is related to the partial flexibility of the linkers.

引用

页码：12614 / +

页数：3

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