An illustration of the limit of the metal organic framework's isoreticular principle using a semirigid tritopic linker obtained by "Click" chemistry

被引:57
作者
Devic, Thomas [1 ]
David, Olivier [1 ]
Valls, Marion [1 ]
Marrot, Jerome [1 ]
Couty, Francois [1 ]
Ferey, Gerard [1 ]
机构
[1] Univ Versailles, Inst Lavoisier, CNRS, UMR 8180, F-78035 Versailles, France
关键词
D O I
10.1021/ja0744091
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new nitrogen-rich tricarboxylate linker was prepared by "click" chemistry and used for the preparation of a lanthanum-based open metal organic framework. This latter is built of inorganic 1-D rods connected through the tritopic linkers and illustrates one limit of the isoreticular principle, which is related to the partial flexibility of the linkers.
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收藏
页码:12614 / +
页数:3
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