Efficient Synthesis of Panchromatic Dyes for Energy Concentration

被引:73
作者
Bura, Thomas [1 ]
Retailleau, Pascal [2 ]
Ziessel, Raymond [1 ]
机构
[1] CNRS, Ecole Europeenne Chim Polymeres & Mat, Lab Chim Mol & Spect Avancees LCOSA, F-67087 Strasbourg 02, France
[2] ICSN CNRS, Cristallochim Lab, Gif Sur Yvette, France
关键词
dyes/pigments; energy transfer; fluorescence; formylation; iterative synthesis; BODIPY DYES; DISTYRYL-BORADIAZAINDACENES; EXCITATION-ENERGY; CHEMISTRY; ARRAYS; DENDRIMER; DEVICES;
D O I
10.1002/anie.201003206
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Channel your energy: Bodipy dyes were linked covalently by a method involving three key steps, including a carboformylation reaction. All multichromophoric dyes exhibited highly efficient photoinduced energy transfer to the terminal Bodipy modules, which fluoresced at 652 nm with 57 □ % quantum efficiency (see absorption (gray) and emission (orange) spectra of a dye containing five Bodipy units). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:6659 / 6663
页数:5
相关论文
共 33 条
[1]  
[Anonymous], 2002, Molecular Mechanisms of Photosynthesis
[2]   The future of energy supply: Challenges and opportunities [J].
Armaroli, Nicola ;
Balzani, Vincenzo .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (1-2) :52-66
[3]   Water soluble distyryl-boradiazaindacenes as efficient photosensitizers for photodynamic therapy [J].
Atilgan, Serdar ;
Ekmekci, Zeynep ;
Dogan, A. Lale ;
Guc, Dicle ;
Akkaya, Engin U. .
CHEMICAL COMMUNICATIONS, 2006, (42) :4398-4400
[4]   Probing intramolecular Forster resonance energy transfer in a naphthaleneimide-peryleneimide-terrylenediimide-based dendrimer by ensemble and single-molecule fluorescence spectroscopy [J].
Cotlet, M ;
Vosch, T ;
Habuchi, S ;
Weil, T ;
Müllen, K ;
Hofkens, J ;
De Schryver, F .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (27) :9760-9768
[5]   Star-Shaped Multichromophoric Arrays from Bodipy Dyes Grafted on Truxene Core [J].
Diring, Stephane ;
Puntoriero, Fausto ;
Nastasi, Francesco ;
Campagna, Sebastiano ;
Ziessel, Raymond .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (17) :6108-+
[6]   Distyryl-boradiazaindacenes: facile synthesis of novel near IR emitting fluorophores [J].
Dost, Zeynep ;
Atilgan, Serdar ;
Akkaya, Engin U. .
TETRAHEDRON, 2006, 62 (36) :8484-8488
[7]   Tetrahedral boron chemistry for the preparation of highly efficient "Cascatelle" devices [J].
Goze, Christine ;
Ulrich, Gilles ;
Ziessel, Raymond .
JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (02) :313-322
[8]   Unusual fluorescent monomeric and dimeric dialkynyl dipyrromethene-borane complexes [J].
Goze, Christine ;
Ulrich, Gilles ;
Ziessel, Raymond .
ORGANIC LETTERS, 2006, 8 (20) :4444-4448
[9]  
Harriman A., 2006, Carbon-Rich Compounds: From Molecules to Materials, P26
[10]   Length Dependence for Intramolecular Energy Transfer in Three- and Four-Color Donor-Spacer-Acceptor Arrays [J].
Harriman, Anthony ;
Mallon, Laura J. ;
Elliot, Kristopher J. ;
Haefele, Alexandre ;
Ulrich, Gilles ;
Ziessel, Raymond .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (37) :13375-13386