Ruthenium-catalyzed reactions for organic synthesis

被引：993

作者：

Naota, T ^{[1
]}

Takaya, H ^{[1
]}

Murahashi, SI ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn Sci, Dept Chem, Toyonaka, Osaka 5608531, Japan

来源：

CHEMICAL REVIEWS | 1998年 / 98卷 / 07期

关键词：

D O I：

10.1021/cr9403695

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Organic syntheses promoted by ruthenium catalysts are reviewed. Since ruthenium has 4d75s1 electron configuration, it has the widest scope of oxidation states (from -2 valent in Ru(CO)4 2- to octavalent in RuO4) of all elements of the periodic table, and various coordination geometries in each electron configuration, which is in contrast to the narrow scope of oxidation states and simple square planar structure of palladium. A number of homogeneous and heterogeneous ruthenium complexes catalyze hydrogenation of various substrates including functionalized olefins, aldehydes, ketones, other carbonyl compounds, and nitro compounds. Great progress has been made on the asymmetric hydrogenations with homogeneous ruthenium complexes bearing chiral phosphine ligands. The chiral diamine-ruthenium complexes also catalyze asymmetric reduction of imines with a formic acid-triethylamine mixture. This method is useful for asymmetric reduction of cyclic imines, providing a general and convenient route to a various indole alkaloids.

引用

页码：2599 / 2660

页数：62

共 786 条

[31] CATALYTIC REDUCTIONS WITH FORMATE ION UNDER PHASE-TRANSFER CONDITIONS [J].